Highlights of Major Progress on Single-Atom Catalysis in 2017

Single-atom catalysis has rapidly progressed during the last few years. In 2017, single-atom catalysts (SACs) were fabricated with higher metal loadings and designed into more delicate structures. SACs also found wide applications in C1 chemical conversion, such as selective oxidation of methane and conversion of carbon dioxide. Both experimental characterizations and computational modeling revealed the presence of tunable interactions between single atom species and their surrounding chemical environment, and thus SACs may be more effective and more stable than their nanoparticle counterparts. In this mini-review, we summarize the major achievements of SACs into three main aspects: (a) the advanced synthetic methodologies, (b) catalytic performance in C1 chemistry, and (c) strong metal-support interaction induced unexpected durability. These accomplishments will shed new light on the recognition of single-atom catalysis and encourage more efforts to explore potential applications of SACs