Non-starch polysaccharides (NSPs), (arabinoxylans and beta-glucans), a main component of cell walls of barley grain, are a limiting factor for the utilization of barley production. Arabinoxylans are formed by (1→4)-ß-D-xylanopyrosyl units substituted with a-L-arabinofuranose. Arabinoxylans are esterified by ferulic acid. Beta-glucans are formed by ß-(1→3),(1→4)-D-glucans, ß-(1→4) linkages account for ca 70 %, ß-(1→3) for the remaining 30 %. NSP concentration in a barley grain is mainly affected by a genotype, growing environment and intensity of vegetation treatment. NSPs can be a cause of technological and economic problems encountered during brewing. However, their content can be reduced by the addition of relevant hydrolytic enzymes. On ...