The effect of diluting ruthenium by iron in RuxSey catalyst for oxygen reduction

7th Spring Meeting of the International-Society-of-Electrochemistry on Recent Advances in Electrocatalysis and Photoelectrocatalysis, Szczyrk, POLAND, MAR 22-25, 2009International audienceThis study has focused on the synthesis of novel oxygen reduction reaction (ORR) chalcogenide catalysts, with Ru partially replaced by Fe in a cluster-type RuxSey. The catalysts were obtained by thermal decomposition of Ru-3(CO)(12) and Fe(CO)(5) in the presence of Se. As indicated by the XPS data, the composition of catalyst nanoparticles depends on the solvent used (either p-xylene or dichlorobenzene). The presence of iron in synthesized catalysts has been confirmed by both EDAX and XPS. Voltammetric activation of the catalysts results in a partial removal of iron and unreacted selenium from the surface. The ORR performance of electrochemically pre-treated catalysts was evaluated using rotating disk and ring-disk electrodes in a sulfuric acid solution. No major change in the ORR mechanism relative to the Se/Ru catalyst has been observed with Fe-containing catalysts. (C) 2010 Elsevier Ltd. All rights reserved