Genesis of the Koka Gold Deposit in Northwest Eritrea, NE Africa: Constraints from Fluid Inclusions and C–H–O–S Isotopes

The Koka gold deposit is located in the Elababu shear zone between the Nakfa terrane and the Adobha Abiy terrane, NW Eritrea. Based on a paragenetic study, two main stages of gold mineralization were identified in the Koka gold deposit: (1) an early stage of pyrite–chalcopyrite–sphalerite–galena–gold–quartz vein; and (2) a second stage of pyrite–quartz veins. NaCl-aqueous inclusions, CO2-rich inclusions, and three-phase CO2–H2O inclusions occur in the quartz veins at Koka. The ore-bearing quartz veins formed at 268 °C from NaCl–CO2–H2O(–CH4) fluids averaging 5 wt% NaCl eq. The ore-forming mechanisms include fluid immiscibility during stage I, and mixing with meteoric water during stage II. Oxygen, hydrogen, and carbon isotopes suggest that the ore-forming fluids originated as mixtures of metamorphic water and magmatic water, whereas the sulfur isotope suggests an igneous origin. The features of geology and ore-forming fluid at the Koka deposit are similar to those of orogenic gold deposits, suggesting that the Koka deposit might be an orogenic gold deposit related to granite