The reaction network of n-butane selective oxidation was comparatively analyzed over a novel αII-V0.8W0.2OPO4 orthophosphate and a reference vanadyl pyrophosphate (VPP) based catalyst via parameter field studies (T = 360–420 °C, x(n-butane) = 0.5–2.0%, x(O2) = 10–20%) as well as cofeed and pulse experiments with presumed reaction intermediates. For VPP the selectivity to the target product maleic anhydride (MAN) is particularly sensitive to the reaction temperature, the n-butane concentration, and the amount of cofed H2O, whereas the selectivity to MAN over the W-containing catalyst is almost independent of all reaction parameters. The roles of 1-butene, acetylene, furan, acetaldehyde, water, and 2,5-dihydrofuran are discussed. Pulsing of p...
The mechanism of the selective partial oxidation of n-butane, but-1-ene and but-1,3-diene over a van...
The anaerobic oxidation of CO by a (VO)2P2O7 catalyst has been used to investigate the nature of the...
Vanadium phosphorus oxide (VPO) was prepared using the precipitation procedure and tested for potent...
Vanadium phosphorus oxide (VPO) catalyst is famously known to catalyze the selective oxidation of n-...
Vanadium phosphorus oxide (VPO) catalyst is famously known to catalyze the selective oxidation of n-...
The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butan...
A good correlation of n-butane conversion and V4+ phase was observed. This suggested that V4+ is hig...
The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butan...
The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butan...
The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butan...
Vanadium phosphate catalysts were synthesized via VOPO42H2O and were calcined in two different hydro...
Vanadium phosphate catalysts were synthesized via VOPO42H2O and were calcined in two different hydro...
The interaction of n-butane with a ((VO)2P2O7) catalyst has been investigated by temperature-program...
Vanadium phosphates have been established as selective hydrocarbon oxidation catalysts for more than...
The surface acidity of two (VO)2P2O7 catalysts with similar specific activities per square meter of ...
The mechanism of the selective partial oxidation of n-butane, but-1-ene and but-1,3-diene over a van...
The anaerobic oxidation of CO by a (VO)2P2O7 catalyst has been used to investigate the nature of the...
Vanadium phosphorus oxide (VPO) was prepared using the precipitation procedure and tested for potent...
Vanadium phosphorus oxide (VPO) catalyst is famously known to catalyze the selective oxidation of n-...
Vanadium phosphorus oxide (VPO) catalyst is famously known to catalyze the selective oxidation of n-...
The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butan...
A good correlation of n-butane conversion and V4+ phase was observed. This suggested that V4+ is hig...
The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butan...
The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butan...
The nature and the role of oxygen species and vanadium oxidation states on the activation of n-butan...
Vanadium phosphate catalysts were synthesized via VOPO42H2O and were calcined in two different hydro...
Vanadium phosphate catalysts were synthesized via VOPO42H2O and were calcined in two different hydro...
The interaction of n-butane with a ((VO)2P2O7) catalyst has been investigated by temperature-program...
Vanadium phosphates have been established as selective hydrocarbon oxidation catalysts for more than...
The surface acidity of two (VO)2P2O7 catalysts with similar specific activities per square meter of ...
The mechanism of the selective partial oxidation of n-butane, but-1-ene and but-1,3-diene over a van...
The anaerobic oxidation of CO by a (VO)2P2O7 catalyst has been used to investigate the nature of the...
Vanadium phosphorus oxide (VPO) was prepared using the precipitation procedure and tested for potent...