Nitrogen-Doped Graphene-Encapsulated Nickel Cobalt Nitride as a Highly Sensitive and Selective Electrode for Glucose and Hydrogen Peroxide Sensing Applications

To explore a natural nonenzymatic electrode catalyst for highly sensitive and selective molecular detection for targeting biomolecules is a very challenging task. Metal nitrides have attracted huge interest as promising electrodes for glucose and hydrogen peroxide (H2O2) sensing applications due to their exceptional redox properties, superior electrical conductivity, and superb mechanical strength. However, the deprived electrochemical stability extremely limits the commercialization opportunities. Herein, novel nitrogen-doped graphene-encapsulated nickel cobalt nitride (NixCo3–xN/NG) core–shell nanostructures with a controllable molar ratio of Ni/Co are successfully fabricated and employed as highly sensitive and selective electrodes for glucose and H2O2 sensing applications. The highly sensitive and selective properties of the optimized core–shell NiCo2N/NG electrode are because of the high synergistic effect of the NiCo2N core and the NG shell, as evidenced by a superior glucose sensing performance with a short response time of