Improved Room Temperature NO₂ Sensing Performance of Organic Field-Effect Transistor by Directly Blending a Hole-Transporting/Electron-Blocking Polymer into the Active Layer

Over the past decades, organic field-effect transistor (OFET) gas sensors have maintained a rapid development. However, the majority of OFET gas sensors show insufficient detection capability towards oxidizing gases such as nitrogen oxide, compared with the inorganic counterpart. In this paper, a new strategy of OFET nitrogen dioxide (NO2) gas sensor, consisting of poly­(3-hexylthiophene-2,5-diyl) (P3HT) and poly­(9-vinylcarbazole) (PVK) blend, is reported. Depending on the gate voltage, this sensor can operate in two modes at room temperature. Of the two modes exposed to NO2 for 5 min, when the gate voltage is 0 V, the highest NO2 responsivity of this OFET is >20 000% for 30 ppm (≈700% for 600 ppb) with the 1:1 P3HT/PVK blend, it is ≈40 times greater than that with the pure P3HT. The limit of detection of ≈300 ppb is achieved, and there is still room for improvement. While in the condition of −40 V, the response increases by 15 times than that with the pure P3HT. This is the first attempt to improve the OFET sensing performance using PVK, which usually functions as a hole-transport layer in the light- emitting device. The enhancement of sensing performance is attributed to the aggregation-controlling and hole-transporting/electron-blocking effect of PVK. This work demonstrates that the hole-transport material can be applied to improve the NO2 sensor with simple solution process, which expands the material choice of OFET gas sensors