The integration of molecules with irregular shape into a long-range, dense and periodic lattice represents a unique challenge for the fabrication of engineered molecular scale architectures. The tiling of pentagonal molecules on a two-dimensional (2D) plane can be used as a proof-of-principle investigation to overcome this problem because basic geometry dictates that a 2D surface cannot be filled with a periodic arrangement of pentagons, a fundamental limitation that suggests that pentagonal molecules may not be suitable as building blocks for dense films. However, here we show that the 2D covalent organic framework (COF) known as COF-1 can direct the growth of pentagonal guest molecules as dense crystalline films at the solution/solid inte...
\u3cp\u3eInterlayer interactions play an important role in the formation of two-dimensional covalent...
Two-dimensional (2D) nanomaterials, such as graphene and single layer covalent organic frameworks (s...
Self-organized molecular films with long-range quasiperiodic order have been grown by using the comp...
Two-dimensional layered covalent organic frameworks (2D COFs) organize π-electron systems into order...
Covalent organic frameworks (COFs), formed by reversible condensation of rigid organic building bloc...
Two-dimensional (2D) polymers assemble organic subunits into covalently linked, high-aspect-ratio ne...
Covalent organic frameworks, although only studied for ten years, have found their way into hydrogen...
Concepts of close packing in monolayers of 5-fold-symmetric buckybowls are discussed. When the symme...
Achieving precise control of molecular self-assembly to form designed three-dimensional (3D) structu...
Two-dimensional (2D) covalent organic frameworks (COFs) represent an emerging class of nanomaterials...
The concept of reticular chemistry is investigated to explore the applicability of the formation of ...
We report the design and synthesis of an imine-based two-dimensional covalent organic framework (2D ...
Covalent organic frameworks (COFs) are an emerging class of highly ordered porous polymers with many...
This study shows that surface-supported two-dimensional (2D) porous covalent organic frameworks (COF...
The study of organic chemistry has enabled remarkable control in the design of zerodimensional molec...
\u3cp\u3eInterlayer interactions play an important role in the formation of two-dimensional covalent...
Two-dimensional (2D) nanomaterials, such as graphene and single layer covalent organic frameworks (s...
Self-organized molecular films with long-range quasiperiodic order have been grown by using the comp...
Two-dimensional layered covalent organic frameworks (2D COFs) organize π-electron systems into order...
Covalent organic frameworks (COFs), formed by reversible condensation of rigid organic building bloc...
Two-dimensional (2D) polymers assemble organic subunits into covalently linked, high-aspect-ratio ne...
Covalent organic frameworks, although only studied for ten years, have found their way into hydrogen...
Concepts of close packing in monolayers of 5-fold-symmetric buckybowls are discussed. When the symme...
Achieving precise control of molecular self-assembly to form designed three-dimensional (3D) structu...
Two-dimensional (2D) covalent organic frameworks (COFs) represent an emerging class of nanomaterials...
The concept of reticular chemistry is investigated to explore the applicability of the formation of ...
We report the design and synthesis of an imine-based two-dimensional covalent organic framework (2D ...
Covalent organic frameworks (COFs) are an emerging class of highly ordered porous polymers with many...
This study shows that surface-supported two-dimensional (2D) porous covalent organic frameworks (COF...
The study of organic chemistry has enabled remarkable control in the design of zerodimensional molec...
\u3cp\u3eInterlayer interactions play an important role in the formation of two-dimensional covalent...
Two-dimensional (2D) nanomaterials, such as graphene and single layer covalent organic frameworks (s...
Self-organized molecular films with long-range quasiperiodic order have been grown by using the comp...