A new discrete hexagonal metallacycle M containing tris-[2]pseudorotaxane moiety has been successfully designed and synthesized via coordination-driven self-assembly. The newly designed tris-[2]pseudorotaxane metallacycle was well characterized with nuclear magnetic resonance and mass spectra analysis. Such tris-[2]pseudorotaxane metallacycle M and pillar[5]arene dimer (PD) could further form a new family of cross-linked redox-responsive supramolecular polymer M⊃(PD)3 through a host–guest interaction. Interestingly, the polymer M⊃(PD)3 displayed redox-responsive behavior and showed tuned weight-average diffusion coefficients D upon redox stimuli, which is attributed to the changed coordination geometries of [Cu(phen)2]+ and [Cu(phen)2...
To investigate the supramolecular interactions of the mechanically interlocked rotaxane pendants and...
The metal-driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing re...
The thesis documents the use of the mild functional-group tolerant copper(I) catalysed azide-alkyne ...
Metallosupramolecular polymer, an appealing polymeric material, plays important roles in many fields...
A new family of discrete hexakis-pillar[5]arene metallacycles with different sizes have been succes...
An emerging strategy for the fabrication of advanced supramolecular materials is the use of hierarch...
A novel bis(<i>m</i>-phenylene)-32-crown-10 derivative bearing two π-extended pyridyl groups was sy...
The design and self-assembly of novel multipyrene hexagonal metallacycles via coordination-driven se...
[[abstract]]A novel M2L4 tetragonal metalloprism, [(NO3-)subset of{Cu-2(mu-Hdpma)(4)}(NO3)(2)](NO3)(...
ABSTRACT: To investigate the supramolecular interactions of the mechanically interlocked rotaxane pe...
This paper reports a synthetic strategy to construct one- and two-dimensional (ID and 2D) polyrotaxa...
International audienceThe design and synthesis of a supramolecular square composed of polyoxometalat...
The metal-driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing...
Herein, we report the preparation of a multifunctional metallacage-core supramolecular gel by orthog...
Research on synthesizing new coordination-driven polyrotaxanes as well as regulating their structura...
To investigate the supramolecular interactions of the mechanically interlocked rotaxane pendants and...
The metal-driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing re...
The thesis documents the use of the mild functional-group tolerant copper(I) catalysed azide-alkyne ...
Metallosupramolecular polymer, an appealing polymeric material, plays important roles in many fields...
A new family of discrete hexakis-pillar[5]arene metallacycles with different sizes have been succes...
An emerging strategy for the fabrication of advanced supramolecular materials is the use of hierarch...
A novel bis(<i>m</i>-phenylene)-32-crown-10 derivative bearing two π-extended pyridyl groups was sy...
The design and self-assembly of novel multipyrene hexagonal metallacycles via coordination-driven se...
[[abstract]]A novel M2L4 tetragonal metalloprism, [(NO3-)subset of{Cu-2(mu-Hdpma)(4)}(NO3)(2)](NO3)(...
ABSTRACT: To investigate the supramolecular interactions of the mechanically interlocked rotaxane pe...
This paper reports a synthetic strategy to construct one- and two-dimensional (ID and 2D) polyrotaxa...
International audienceThe design and synthesis of a supramolecular square composed of polyoxometalat...
The metal-driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing...
Herein, we report the preparation of a multifunctional metallacage-core supramolecular gel by orthog...
Research on synthesizing new coordination-driven polyrotaxanes as well as regulating their structura...
To investigate the supramolecular interactions of the mechanically interlocked rotaxane pendants and...
The metal-driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing re...
The thesis documents the use of the mild functional-group tolerant copper(I) catalysed azide-alkyne ...