Highly Conductive Hydrogel Polymer Fibers toward Promising Wearable Thermoelectric Energy Harvesting

The requirement of a portable electron is functioning as a driving force for a wearable energy instrument. Poly­(3,4-ethylenedioxythiophene):poly­(styrenesulfonate) (PEDOT:PSS), as one of the most promising organic electron materials, has been widely studied in energy conversion devices. However, the efforts for PEDOT:PSS fibers are insufficient to boost the development of wearable thermoelectric energy harvesting. Here, a highly conductive p-type PEDOT:PSS fiber was produced by gelation process, which was 3 orders of magnitude higher than that of previous hydrogel fibers. Surprisingly, a post-treatment with organic solvents such as ethylene glycol and dimethyl sulfoxide tripled their electrical conductivity with an only 5% decreased Seebeck coefficient, consequently leading to an optimized thermoelectric power factor. Furthermore, we assembled a p–n-type thermoelectric device connecting five pairs of p-type PEDOT:PSS fibers and n-type carbon nanotube fibers. This fiber-based device displayed an acceptable output voltage of 20.7 mV and a power density of 481.2 μW·cm–2 with a temperature difference of ∼60 K, which might pave the way for the development of organic thermoelectric fibers for wearable energy harvesting