A previously reported cobalt complex featuring a tetraimidazolyl-substituted pyridine chelate is an active water oxidation electrocatalyst with moderate overpotential at pH 7. While this complex decomposes rapidly to a less-active species under electrocatalytic conditions, detailed electrochemical studies support the agency of an initial molecular catalyst. Cyclic voltammetry measurements confirm that the imidazolyl donors result in a more electron-rich Co center when compared with previous pyridine-based systems. The primary changes in electrocatalytic behavior of the present case are enhanced activity at lower pH and a marked dependence of catalytic activity on pH
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
The electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated polypyridyl cobalt(ii...
A previously reported cobalt complex featuring a tetraimidazolyl-substituted pyridine chelate is an ...
A detailed investigation of the cobalt corrole Co(tpfc) as molecular catalyst for electrochemical w...
A cobalt bis(iminopyridine) complex is a highly active electrocatalyst for water reduction, with an ...
The chemistry of the electrocatalytic reduction of CO<sub>2</sub> using nitrogen containing heteroar...
Cobalt oxides are an earth abundant material that exhibits high electrocatalytic activity for the ox...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
Cobalt oxides are an earth abundant material that exhibits high electrocatalytic activity for the ox...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
The electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated polypyridyl cobalt(ii...
A previously reported cobalt complex featuring a tetraimidazolyl-substituted pyridine chelate is an ...
A detailed investigation of the cobalt corrole Co(tpfc) as molecular catalyst for electrochemical w...
A cobalt bis(iminopyridine) complex is a highly active electrocatalyst for water reduction, with an ...
The chemistry of the electrocatalytic reduction of CO<sub>2</sub> using nitrogen containing heteroar...
Cobalt oxides are an earth abundant material that exhibits high electrocatalytic activity for the ox...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
Cobalt oxides are an earth abundant material that exhibits high electrocatalytic activity for the ox...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
International audienceThe electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated...
The electrochemical behavior of [Co(bapbpy)Cl](+)[1-Cl](+), a pentacoordinated polypyridyl cobalt(ii...