The iodine–metal exchange reaction on cubane was examined using various lithium organozincates. Among these, the dianionic zincate, n-Bu4ZnLi2, gave optimum results. The resulting cubyl metal species could be converted into various cubane derivatives via addition reactions with electrophiles, such as an organohalide or aldehyde. The potential functional group tolerance of organozincates lends this protocol to the synthesis of polyfunctionalized cubane derivatives
Pioneered by Wanklyn more than 150 years ago, organozincates have recently emerged as a versatile an...
In a study aimed at developing the diisopropylamido (DA) chemistry of zincates, the new lithium DA-z...
WOS: 000188066400021Metal-halogen exchange between Ph2CuLi . LiCN and ortho-substituted aryl iodides...
The iodine-metal exchange reaction on cubane was examined using various lithium organozincates. Amon...
The methods described herein deal with the problem of precluding protection/deprotection and functio...
International audienceMetalation of N-phenylpyrrole using an in situ mixture of ZnCl2*TMEDA (0.5 equ...
A wide range of polyfunctional diaryl-and diheteroarylzinc species were prepared in toluene within 1...
Multifunctional organic molecules can be achieved by reacting functionalized organolithium compounds...
Organozinc and copper derivatives are useful reagents in organic synthesis. Because of the high func...
This study investigates the ability of the mixed-metal reagent [Li(TMP)Zn(tBu)(2)] 1 to promote dire...
Highly reactive zinc was prepared by the lithium naphthalenide reduction of zinc halides. This highl...
$unm~. The new copper eagent RCu(CN)ZnI 2, which may contain important functional groups like the es...
Functionalized aromatic iodides possessing an ester, cyano, chloride or keto group can be converted ...
International audienceHomoleptic lithium tri- and tetraalkyl zincates were reacted with a set of bro...
International audienceThe metallation of aryl ketones was achieved by using LiTMP in the presence of...
Pioneered by Wanklyn more than 150 years ago, organozincates have recently emerged as a versatile an...
In a study aimed at developing the diisopropylamido (DA) chemistry of zincates, the new lithium DA-z...
WOS: 000188066400021Metal-halogen exchange between Ph2CuLi . LiCN and ortho-substituted aryl iodides...
The iodine-metal exchange reaction on cubane was examined using various lithium organozincates. Amon...
The methods described herein deal with the problem of precluding protection/deprotection and functio...
International audienceMetalation of N-phenylpyrrole using an in situ mixture of ZnCl2*TMEDA (0.5 equ...
A wide range of polyfunctional diaryl-and diheteroarylzinc species were prepared in toluene within 1...
Multifunctional organic molecules can be achieved by reacting functionalized organolithium compounds...
Organozinc and copper derivatives are useful reagents in organic synthesis. Because of the high func...
This study investigates the ability of the mixed-metal reagent [Li(TMP)Zn(tBu)(2)] 1 to promote dire...
Highly reactive zinc was prepared by the lithium naphthalenide reduction of zinc halides. This highl...
$unm~. The new copper eagent RCu(CN)ZnI 2, which may contain important functional groups like the es...
Functionalized aromatic iodides possessing an ester, cyano, chloride or keto group can be converted ...
International audienceHomoleptic lithium tri- and tetraalkyl zincates were reacted with a set of bro...
International audienceThe metallation of aryl ketones was achieved by using LiTMP in the presence of...
Pioneered by Wanklyn more than 150 years ago, organozincates have recently emerged as a versatile an...
In a study aimed at developing the diisopropylamido (DA) chemistry of zincates, the new lithium DA-z...
WOS: 000188066400021Metal-halogen exchange between Ph2CuLi . LiCN and ortho-substituted aryl iodides...