Unusual Reactivity of Isoquinolinones Generated by Silver-Catalyzed Cycloisomerizations of Imines Derived from <i>ortho</i>-Alkynylsalicylaldehydes

8-Isoquinolinones derived from a silver-catalyzed cycloisomerization of in situ formed ortho-alkynyl­salicylaldimines react with 1 equiv of acetylene­dicarboxylate derivatives to give pyrano­[2,3,4-ij]­isoquinolines through a [4 + 2]-cycloaddition reaction. When 2 equiv of the alkyne are used, structurally complex benzo­[de]­chromenes are obtained through an intricate cascade process comprising unusual formal [4 + 2]- and [2 + 2]-cycloadditions followed by several ring-opening and ring-closing processes