A series of trinuclear and dinuclear Cr(I)–N2 complexes bearing cyclopentadienyl-phosphine ligands were synthesized and characterized. Further reduction of the Cr(I)–N2 complexes generated anionic Cr(0)–N2 complexes, which could react with Me3SiCl to afford the first chromium hydrazido complex from N2 functionalization. These complexes were found to be effective catalysts for the transformation of N2 into N(SiMe3)3
This review presents a comprehensive overview of the reactions of N-2 within the coordination sphere...
The direct use of dinitrogen (N2) as a building block for the synthesis of NN-containing organic com...
Final published version.Dinitrogen complexes of the type TpR,RCr???N2???CrTpR,R are not the most lab...
A series of trinuclear and dinuclear Cr(I)–N2 complexes bearing cyclopentadienyl-phosphine ligands ...
Isolation of key intermediate complexes in dinitrogen functionalization is crucial for elucidating t...
Theopold, Klaus H.This dissertation describes research on paramagnetic chromium complexes coordinate...
Reduction of 2,6-[2,6-(i-Pr)2PhN=C(CH3)]2(C5H3N)CrCl (3) with NaH afforded the dinuclear dinitrogen ...
We report a rare example of a Cr–N<sub>2</sub> complex supported by a 16-membered phosphorus macrocy...
A family of zirconocene and hafnocene compounds bearing side-on bound dinitrogen ligands were prepar...
Direct conversion of dinitrogen (N2) into organic compounds, not through ammonia (NH3), is of great ...
Indenyl zirconocene dinitrogen complexes were synthesized from the direct activation of N2 by isolab...
Direct conversion of dinitrogen (N-2) into organic compounds, not through ammonia (NH3), is of great...
Aryl-based chelates containing oxazoline or imine donors were synthesized, and their reactivity with...
Molecular nitrogen comprises about 80% of the earth’s atmosphere, but is only used as a starling ma...
The activation of iodomethane by the Cr(II) complex 1 to form the Cr(III) iodide and Cr(III) methyl ...
This review presents a comprehensive overview of the reactions of N-2 within the coordination sphere...
The direct use of dinitrogen (N2) as a building block for the synthesis of NN-containing organic com...
Final published version.Dinitrogen complexes of the type TpR,RCr???N2???CrTpR,R are not the most lab...
A series of trinuclear and dinuclear Cr(I)–N2 complexes bearing cyclopentadienyl-phosphine ligands ...
Isolation of key intermediate complexes in dinitrogen functionalization is crucial for elucidating t...
Theopold, Klaus H.This dissertation describes research on paramagnetic chromium complexes coordinate...
Reduction of 2,6-[2,6-(i-Pr)2PhN=C(CH3)]2(C5H3N)CrCl (3) with NaH afforded the dinuclear dinitrogen ...
We report a rare example of a Cr–N<sub>2</sub> complex supported by a 16-membered phosphorus macrocy...
A family of zirconocene and hafnocene compounds bearing side-on bound dinitrogen ligands were prepar...
Direct conversion of dinitrogen (N2) into organic compounds, not through ammonia (NH3), is of great ...
Indenyl zirconocene dinitrogen complexes were synthesized from the direct activation of N2 by isolab...
Direct conversion of dinitrogen (N-2) into organic compounds, not through ammonia (NH3), is of great...
Aryl-based chelates containing oxazoline or imine donors were synthesized, and their reactivity with...
Molecular nitrogen comprises about 80% of the earth’s atmosphere, but is only used as a starling ma...
The activation of iodomethane by the Cr(II) complex 1 to form the Cr(III) iodide and Cr(III) methyl ...
This review presents a comprehensive overview of the reactions of N-2 within the coordination sphere...
The direct use of dinitrogen (N2) as a building block for the synthesis of NN-containing organic com...
Final published version.Dinitrogen complexes of the type TpR,RCr???N2???CrTpR,R are not the most lab...