Microporous polymer membranes (MPMs) are attractive for gas separation due to their high porosity and tuneable functionalization. In this study, two new MPMs (namely PILP-1 and PILP-3) are designed with the contorted linkers as in polymers of intrinsic microporosity (PIMs) and the tetrahedral cores as in benzimidazole-linked polymers. The separation performance of PILP-1 and PILP-3 for a CO2/CH4 mixture is investigated by molecular dynamics (MD) simulation under a constant pressure gradient. Unlike conventional MD simulation, our simulation incorporates both polymer flexibility and membrane plasticization during gas permeation. The simulation results are found to agree well with the available experimental data. PILP-1 and PILP-3 are predict...
The potential of an ultrapermeable benzotriptycene-based polymer of intrinsic microporosity (PIM-TMN...
Molecular modeling techniques were used to investigate the permeability and selectivity of various n...
Sorption of pure methane, carbon dioxide and their binary mixtures in two glassy polymers, poly(1-tr...
When polymeric membranes are employed to remove selectively one component from a gaseous mixture, th...
This manuscript describes the gas separation performance of PIM-2, a partially fluorinated linear co...
Polymers of Intrinsic Microporosity (PIMs) combine the desirable processability of polymers with a ...
Gas separation with membranes has been commercialized for more than 30 years, and includes processes...
Greenhouse gas separation, storage, and utilization are extremely urgent due to the growing climate ...
The promise of ultrapermeable polymers, such as poly(trimethylsilylpropyne) (PTMSP), for reducing th...
Pure-gas transport performance rarely matches mixed-gas performance for industrially relevant membra...
none3noThe gas solubility in polymeric membranes affects the separation performance, particularly in...
© 2015 by the authors; licensee MDPI, Basel, Switzerland.We study the permeation dynamics of helium ...
Efficient separation of CO2 from CO2/CH4 mixtures using membranes has economic, environmental and in...
Membranes composed of Polymers of Intrinsic Microporosity (SBF-PIMs) have potential for commercial g...
International audienceThis work illustrates the potential of using atomistic molecular dynamics (MD)...
The potential of an ultrapermeable benzotriptycene-based polymer of intrinsic microporosity (PIM-TMN...
Molecular modeling techniques were used to investigate the permeability and selectivity of various n...
Sorption of pure methane, carbon dioxide and their binary mixtures in two glassy polymers, poly(1-tr...
When polymeric membranes are employed to remove selectively one component from a gaseous mixture, th...
This manuscript describes the gas separation performance of PIM-2, a partially fluorinated linear co...
Polymers of Intrinsic Microporosity (PIMs) combine the desirable processability of polymers with a ...
Gas separation with membranes has been commercialized for more than 30 years, and includes processes...
Greenhouse gas separation, storage, and utilization are extremely urgent due to the growing climate ...
The promise of ultrapermeable polymers, such as poly(trimethylsilylpropyne) (PTMSP), for reducing th...
Pure-gas transport performance rarely matches mixed-gas performance for industrially relevant membra...
none3noThe gas solubility in polymeric membranes affects the separation performance, particularly in...
© 2015 by the authors; licensee MDPI, Basel, Switzerland.We study the permeation dynamics of helium ...
Efficient separation of CO2 from CO2/CH4 mixtures using membranes has economic, environmental and in...
Membranes composed of Polymers of Intrinsic Microporosity (SBF-PIMs) have potential for commercial g...
International audienceThis work illustrates the potential of using atomistic molecular dynamics (MD)...
The potential of an ultrapermeable benzotriptycene-based polymer of intrinsic microporosity (PIM-TMN...
Molecular modeling techniques were used to investigate the permeability and selectivity of various n...
Sorption of pure methane, carbon dioxide and their binary mixtures in two glassy polymers, poly(1-tr...