Boosting Superconducting Properties of Fe(Se, Te) via Dual-Oscillation Phenomena Induced by Fluorine Doping

Fluorine-doped Fe­(Se, Te) has been successfully synthesized using the melting method. A dual-oscillation effect was found in the F-doped sample, which combined both microstructural oscillation and chemical compositional oscillation. The microstructural oscillation could be attributed to alternate growth of tetragonal β-Fe­(Se, Te) and hexagonal δ-Fe­(Se, Te), which formed a pearlite-like structure and led to the enhancement of δl flux pinning due to the alternating distributed nonsuperconducting δ-Fe­(Se, Te) phase. The chemical compositional oscillations in β-Fe­(Se, Te) phase were because of the inhomogeneously distributed Se and Te, which changes the pinning mechanism from surface pinning in the undoped sample to Δκ pinning in the 5% F-doped one. As a result, the critical current, upper critical field, and thermally activated flux-flow activation energy of FeSe0.45Te0.5F0.05 were enhanced by 7, 2, and 3 times, respectively. Our work revealed the physical insights into F-doping resulting in high-performance Fe­(Se, Te) superconductors and inspired a new approach to optimize superconductivities in iron-based superconductors through phase and element manipulations