The dissolution behavior of uranyl peroxide studtite, [(UO2)(O2)(H2O)2](H2O)2, was examined under a wide range of alkaline aqueous environments with and without the addition of hydrogen peroxide. In the absence of added H2O2, studtite dissolved in aqueous solutions with a tetraethylammonium hydroxide to uranium molar ratio greater than 0.5, and the resulting species in solution characterized by Raman spectroscopy and electrospray ionization mass spectrometry (ESI-MS) is the uranyl peroxide nanocluster U24, [(UO2)(O2)(OH)]2424–. This is the first demonstration of the formation of uranyl peroxide nanoclusters from studtite in a solution lacking additional hydrogen peroxide. In similar systems containing added hydrogen peroxide (0.01 M – ...
Herein, we report a new salt of a pyrophosphate-functionalized uranyl peroxide nanocluster {U24Pp12}...
The gas-phase uranyl peroxide dimer, [(UO2)2(O2)(L)2]2+ where L = 2,2’-trifluoroethylazanediyl)bis(N...
Uranyl peroxide compounds are important to the nuclear fuel cycle and are typically formed from the ...
Understanding the stability fields and decomposition products of various metal- and actinide-oxide n...
Understanding the stability fields and decomposition products of various metal- and actinide-oxide n...
Solid UO<sub>2</sub> dissolution and uranium speciation in aqueous solutions that promote formation ...
Dissolution of uranium materials in alkaline aqueous conditions containing H2O2 results in uranyl pe...
The first four uranyl peroxide compounds containing ethylenediaminetetra-acetate (EDTA) were synthes...
Self-assembly of uranyl peroxide polyoxometalates (POMs) in alkaline peroxide solutions has been kno...
Strategies for interpreting mass spectrometric and Raman spectroscopic data have been developed to s...
Great effort has been made to synthesize larger uranyl peroxide clusters whilst the understanding of...
The presence of uranium-based nanomaterials in environmental systems may significantly impact our cu...
The gas-phase uranyl peroxide dimer, [(UO2)2(O2)(L)2]2+ where L = 2,2'-trifluoroethylazanediyl)bis(N...
The pentagonal K<sub>10</sub>[(UO<sub>2</sub>)<sub>5</sub>(μ-O<sub>2</sub>)<sub>5</sub>(C<sub>2</sub...
Uranyl peroxide cluster species were produced in aqueous solution by the treatment of uranyl nitrate...
Herein, we report a new salt of a pyrophosphate-functionalized uranyl peroxide nanocluster {U24Pp12}...
The gas-phase uranyl peroxide dimer, [(UO2)2(O2)(L)2]2+ where L = 2,2’-trifluoroethylazanediyl)bis(N...
Uranyl peroxide compounds are important to the nuclear fuel cycle and are typically formed from the ...
Understanding the stability fields and decomposition products of various metal- and actinide-oxide n...
Understanding the stability fields and decomposition products of various metal- and actinide-oxide n...
Solid UO<sub>2</sub> dissolution and uranium speciation in aqueous solutions that promote formation ...
Dissolution of uranium materials in alkaline aqueous conditions containing H2O2 results in uranyl pe...
The first four uranyl peroxide compounds containing ethylenediaminetetra-acetate (EDTA) were synthes...
Self-assembly of uranyl peroxide polyoxometalates (POMs) in alkaline peroxide solutions has been kno...
Strategies for interpreting mass spectrometric and Raman spectroscopic data have been developed to s...
Great effort has been made to synthesize larger uranyl peroxide clusters whilst the understanding of...
The presence of uranium-based nanomaterials in environmental systems may significantly impact our cu...
The gas-phase uranyl peroxide dimer, [(UO2)2(O2)(L)2]2+ where L = 2,2'-trifluoroethylazanediyl)bis(N...
The pentagonal K<sub>10</sub>[(UO<sub>2</sub>)<sub>5</sub>(μ-O<sub>2</sub>)<sub>5</sub>(C<sub>2</sub...
Uranyl peroxide cluster species were produced in aqueous solution by the treatment of uranyl nitrate...
Herein, we report a new salt of a pyrophosphate-functionalized uranyl peroxide nanocluster {U24Pp12}...
The gas-phase uranyl peroxide dimer, [(UO2)2(O2)(L)2]2+ where L = 2,2’-trifluoroethylazanediyl)bis(N...
Uranyl peroxide compounds are important to the nuclear fuel cycle and are typically formed from the ...