Pd-Catalyzed C(sp<sup>2</sup>)–H Imidoylative Annulation: A General Approach To Construct Dibenzoox(di)azepines
- Weiming Hu (257720)
- Fan Teng (1581460)
- Huaanzi Hu (3989675)
- Shuang Luo (18856)
- Qiang Zhu (188733)
DOIAbstract
A general method to construct the scaffolds of dibenzooxazepine and dibenzodiazepine, through Pd-catalyzed isocyanide insertion and intramolecular C(sp2)–H activation, has been developed. This is the first example of seven-membered heterocycle formation by C–H imidoylative annulation
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