The technique of pulsed-beam Fourier transform microwave spectroscopy is applied to gas-phase organometallic systems for elucidation of fundamental structural properties of the compounds. Ten organometallic species with significant catalytic and reactive properties are examined and presented. This work includes complete three-dimensional structural determinations of; methylrheniumtrioxide, cyclopentadienylthallium, tetracarbonyldihydroiron, tetracarbonyldihydroruthenium and tetracarbonylethyleneiron. Quadrupole coupling parameters are presented and discussed for the compounds; methylrheniumtrioxide, cyclopentadienylrheniumtricarbonyl, cyclopentadienylindium, 'anti' and ' syn' allyltricarbonylironbromide, chloroferrocene and bromoferrocene. ...
Understanding the nature of chemical bonds constitutes a major theme of this thesis. This thesis inv...
The pure rotational spectrum of difluorochloromethane, Freon 22, has been obtained in the K-band mic...
The pure rotational spectrum of difluorochloromethane, Freon 22, has been obtained in the K-band mic...
This dissertation focuses on the structural investigation of gas phase organometallic complexes, hyd...
High-resolution pulsed beam Fourier Transform Microwave Spectroscopy (PBFTMS) technique has been use...
The microwave spectra were measured in the 4-15 GHz regime for cyclopropanecarboxylic acid, 1,2-cycl...
Gas phase structures and other molecular parameters have been investigated for several molecules and...
Author Institution: Department of Chemistry, University of ArizonaRotational spectra for two isotopo...
Author Institution: Department of Chemistry, University of ArizonaRotational spectra for two isotopo...
High resolution microwave spectra for the transition metal compounds cobalt tri-carbonyl nitrosyl (C...
High resolution rotational spectra were obtained for a several weakly-bound complexes (WBC) and one ...
$^{a}$Supported by THE NATIONAL SCIENCE FOUNDATION.Author Institution: Department of Chemistry, Univ...
Pure rotational microwave spectra of the following molecules have been obtained using a pulsed jet ...
$^{a}$Supported by THE NATIONAL SCIENCE FOUNDATION.Author Institution: Department of Chemistry, Univ...
Pure rotational microwave spectra of the following molecules have been obtained using a pulsed jet ...
Understanding the nature of chemical bonds constitutes a major theme of this thesis. This thesis inv...
The pure rotational spectrum of difluorochloromethane, Freon 22, has been obtained in the K-band mic...
The pure rotational spectrum of difluorochloromethane, Freon 22, has been obtained in the K-band mic...
This dissertation focuses on the structural investigation of gas phase organometallic complexes, hyd...
High-resolution pulsed beam Fourier Transform Microwave Spectroscopy (PBFTMS) technique has been use...
The microwave spectra were measured in the 4-15 GHz regime for cyclopropanecarboxylic acid, 1,2-cycl...
Gas phase structures and other molecular parameters have been investigated for several molecules and...
Author Institution: Department of Chemistry, University of ArizonaRotational spectra for two isotopo...
Author Institution: Department of Chemistry, University of ArizonaRotational spectra for two isotopo...
High resolution microwave spectra for the transition metal compounds cobalt tri-carbonyl nitrosyl (C...
High resolution rotational spectra were obtained for a several weakly-bound complexes (WBC) and one ...
$^{a}$Supported by THE NATIONAL SCIENCE FOUNDATION.Author Institution: Department of Chemistry, Univ...
Pure rotational microwave spectra of the following molecules have been obtained using a pulsed jet ...
$^{a}$Supported by THE NATIONAL SCIENCE FOUNDATION.Author Institution: Department of Chemistry, Univ...
Pure rotational microwave spectra of the following molecules have been obtained using a pulsed jet ...
Understanding the nature of chemical bonds constitutes a major theme of this thesis. This thesis inv...
The pure rotational spectrum of difluorochloromethane, Freon 22, has been obtained in the K-band mic...
The pure rotational spectrum of difluorochloromethane, Freon 22, has been obtained in the K-band mic...