Add to ORKGThe synthesis of the chiral sulfide isothiocineole from limonene and elemental sulfur on multi-gram scale and its alkylation to make >50 g of the corresponding benzylsulfonium salt are described. The application of this salt to the sulfur ylide-mediated asymmetric epoxidation of aldehydes and the asymmetric aziridination of imines on a >5 g scale is demonstrated.Irish Research CouncilScience Foundation IrelandUniversity of BristolMarie-Curie Action COFUN
This review describes advances in the literature since the mid-1990s in the area of reactions of sul...
The sodium salt of (S)-sulfimide 8 reacts with carbonyl compounds to yield (R)-epoxides in 60-64% yi...
Transition-metal-free, sulfur mediated allylic C-H arylation, epoxidation and aziridination were rea...
The synthesis of the chiral sulfide isothiocineole from limonene and elemental sulfur on multi-gram ...
The synthesis of the chiral sulfide isothiocineole from limonene and elemental sulfur on multi-gram ...
The chiral sulfide, isothiocineole, has been synthesized in one step from elemental sulfur, γ-terpin...
Application of two different chiral sulfides m asymmetric cyclopropanation and epoxidation reactions...
Enantiomerically enriched sulfimides are used to prepare enantiomerically enriched epoxides, aziridi...
This thesis describes the design and synthesis of chiral sulfides for use in asymmetric cpoxidations...
Abstract: Coupling of diphenylvinyl sulfonium triflate with nu-cleophiles and either aldehydes or im...
Abstract The first part of this monograph discusses the asymmetric, ylide based, reagent controlle...
This thesis reports findings in two projects utilising sulfur as a chiral auxiliary in asymmetric sy...
Sulfur-based ylides are very important and valuable reagents in organic synthesis and have been wide...
Part A. Several optically active thiolanes were synthesized and converted into sulfonium salts. Thes...
This work describes an expeditious and efficient preparation of enantiopure (thiolan-2-yl)diphenylm...
This review describes advances in the literature since the mid-1990s in the area of reactions of sul...
The sodium salt of (S)-sulfimide 8 reacts with carbonyl compounds to yield (R)-epoxides in 60-64% yi...
Transition-metal-free, sulfur mediated allylic C-H arylation, epoxidation and aziridination were rea...
The synthesis of the chiral sulfide isothiocineole from limonene and elemental sulfur on multi-gram ...
The synthesis of the chiral sulfide isothiocineole from limonene and elemental sulfur on multi-gram ...
The chiral sulfide, isothiocineole, has been synthesized in one step from elemental sulfur, γ-terpin...
Application of two different chiral sulfides m asymmetric cyclopropanation and epoxidation reactions...
Enantiomerically enriched sulfimides are used to prepare enantiomerically enriched epoxides, aziridi...
This thesis describes the design and synthesis of chiral sulfides for use in asymmetric cpoxidations...
Abstract: Coupling of diphenylvinyl sulfonium triflate with nu-cleophiles and either aldehydes or im...
Abstract The first part of this monograph discusses the asymmetric, ylide based, reagent controlle...
This thesis reports findings in two projects utilising sulfur as a chiral auxiliary in asymmetric sy...
Sulfur-based ylides are very important and valuable reagents in organic synthesis and have been wide...
Part A. Several optically active thiolanes were synthesized and converted into sulfonium salts. Thes...
This work describes an expeditious and efficient preparation of enantiopure (thiolan-2-yl)diphenylm...
This review describes advances in the literature since the mid-1990s in the area of reactions of sul...
The sodium salt of (S)-sulfimide 8 reacts with carbonyl compounds to yield (R)-epoxides in 60-64% yi...
Transition-metal-free, sulfur mediated allylic C-H arylation, epoxidation and aziridination were rea...