Magnetic anisotropy in surface-supported single-ion lanthanide complexes

Single-ion lanthanide-organic complexes can provide stable magnetic moments with well-defined orientation for spintronic applications on the atomic level. Here, we show by a combined experimental approach of scanning tunneling microscopy and x-ray absorption spectroscopy that dysprosium- tris(1,1,1-trifluoro-4-(2-thienyl)-2,4- butanedionate) (Dy(tta)3) complexes deposited on a Au(111) surface undergo a molecular distortion, resulting in distinct crystal field symmetry imposed on the Dy ion. This leads to an easy- axis magnetization direction in the ligand plane. Furthermore, we show that tunneling electrons hardly couple to the spin excitations, which we ascribe to the shielded nature of the 4f electrons