Stepwise interactions of photochemically generated M(CO)(5)(THF) (M = Cr, Mo, W) with diferroce-nylditelluride initially generated mononuclear M(CO)(5)(Fc(2)Te(2)) followed by the bimetallic [M(CO)(5)](2)(mu-Fc(2)Te(2)) with terminal and bridged Fc(2)Te(2) moieties, respectively. On photolysis, [M(CO)(5)](2)(mu-Fc(2)Te(2)) transformed to FcTe bridged and M-M bonded "butterfly" complexes [(CO)(4)M(mu-FcTe)(2) via the elimination of two carbonyl groups. The solid state structures and Te-125 NMR spectral data of the new complexes and a new polymorphic form of Fc(2)Te(2) having remarkable intermolecular Te...pi-Cp short contacts (av. 3.5 angstrom) are discussed. (C) 2014 Elsevier B.V. All rights reserved
Thermolysis of a benzene solution containing Fe(CO)5 and ferrocenylacetylene yielded three new compo...
New complexes {M(CO)4[Ph2P(S)P(S)Ph2]} (M = Cr, Mo and W), (1a) - (3a), [(1a), M = Cr; (2a), M = Mo;...
The shortening of partly multiple M-Te (M = Mn, Fe, Co, Cr or W) bonds is observed for two classes o...
The photolytic reaction of (Z)-1-ferrocenyltelluro-1-ferrocenyl-4-ferrocenyl-1-buten-3-yne with iron...
Five new complexes, [M(CO)5(DTTT)] [M = Cr; 1, Mo; 2, W; 3], [Re(CO)4Br(DTTT)] (4) and [Mn(CO)2Cp(DT...
Five new complexes, [M(CO)(5)(DTTT)] [M = Cr; 1, Mo; 2, W; 3], [Re(CO)(4)Br(DTTT)] (4) and [Mn(CO)(2...
Five new complexes, [M(CO)5(DTTT)] [M=Cr; 1, Mo; 2, W; 3], [Re(CO)4Br(DTTT)] (4) and [Mn(CO)2Cp(DTTT...
Depending on the ratio of the starting reagents, the interaction of [FcTeI] with Fe(CO)(5) gave comp...
New complexes of transition metals with organotellurium halide ligands are reported. Iodination of [...
New complexes of transition metals with organotellurium halide ligands are reported. Iodination of [...
Thermolysis of a benzene solution containing Fe(CO)5 and ferrocenylacetylene yielded three new compo...
Photolysis of a benzene solution containing Fe(CO)(5) and [(eta(5)-C5R5)Mo(CO)(3)(Cequivalent toCPh)...
The metal carbonyl complexes, Cp(,2)M(CO)(,2) (M = Zr, Hf) and (C(,5)Me(,5))(,2)M(CO)(,2) (M = Ti, Z...
Photolysis of hexacarbonylmetal(0) complexes of the Group 6 elements in the presence of vinylferroce...
The complexes [M(CO)(4)(eta(2)-H2L)][M Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical re...
Thermolysis of a benzene solution containing Fe(CO)5 and ferrocenylacetylene yielded three new compo...
New complexes {M(CO)4[Ph2P(S)P(S)Ph2]} (M = Cr, Mo and W), (1a) - (3a), [(1a), M = Cr; (2a), M = Mo;...
The shortening of partly multiple M-Te (M = Mn, Fe, Co, Cr or W) bonds is observed for two classes o...
The photolytic reaction of (Z)-1-ferrocenyltelluro-1-ferrocenyl-4-ferrocenyl-1-buten-3-yne with iron...
Five new complexes, [M(CO)5(DTTT)] [M = Cr; 1, Mo; 2, W; 3], [Re(CO)4Br(DTTT)] (4) and [Mn(CO)2Cp(DT...
Five new complexes, [M(CO)(5)(DTTT)] [M = Cr; 1, Mo; 2, W; 3], [Re(CO)(4)Br(DTTT)] (4) and [Mn(CO)(2...
Five new complexes, [M(CO)5(DTTT)] [M=Cr; 1, Mo; 2, W; 3], [Re(CO)4Br(DTTT)] (4) and [Mn(CO)2Cp(DTTT...
Depending on the ratio of the starting reagents, the interaction of [FcTeI] with Fe(CO)(5) gave comp...
New complexes of transition metals with organotellurium halide ligands are reported. Iodination of [...
New complexes of transition metals with organotellurium halide ligands are reported. Iodination of [...
Thermolysis of a benzene solution containing Fe(CO)5 and ferrocenylacetylene yielded three new compo...
Photolysis of a benzene solution containing Fe(CO)(5) and [(eta(5)-C5R5)Mo(CO)(3)(Cequivalent toCPh)...
The metal carbonyl complexes, Cp(,2)M(CO)(,2) (M = Zr, Hf) and (C(,5)Me(,5))(,2)M(CO)(,2) (M = Ti, Z...
Photolysis of hexacarbonylmetal(0) complexes of the Group 6 elements in the presence of vinylferroce...
The complexes [M(CO)(4)(eta(2)-H2L)][M Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical re...
Thermolysis of a benzene solution containing Fe(CO)5 and ferrocenylacetylene yielded three new compo...
New complexes {M(CO)4[Ph2P(S)P(S)Ph2]} (M = Cr, Mo and W), (1a) - (3a), [(1a), M = Cr; (2a), M = Mo;...
The shortening of partly multiple M-Te (M = Mn, Fe, Co, Cr or W) bonds is observed for two classes o...