E-azobenzene bearing electron-withdrawing and ionizable substituents (e.g. 2) exhibits solvatochromic behaviour, high % of Z isomer at photostationary state, and very fast thermal Z --> E isomerization in protic polar solvents. A rotational mechanism has been suggested for the isomerization process
ABSTRACT: Azobenzene functionalized with ortho-fluo-rine atoms has a lower energy of the n-orbital o...
Here we report a photochemical and kinetic study of the thermal relaxation reaction of a double azob...
The photo-induced trans–cis isomerization of the azobenzene derivative 4-nitro-4'-(dimethylamino)azo...
International audienceAzobenzene molecular switches can interconvert both photochemically and therma...
none6noShape-persistent azobenzene tetramers functionalized at the periphery with alkyloxy substitue...
The rates of Z-E isomerization of azobenzene and seven 4-substituted derivatives (CH3, CF3, OCH3, n-...
The E-Z photoisomerization of azobenzene - owing to its high efficiency, excellent reversibility and...
2,2'-Dihydroxyazobenzene (DAB), 2,2'-azotoluene (AT) and azobenzene (AB) were isolated in argon and ...
The influence of substituents and media polarity on the photoinducedE→Z geometrical isomerisation of...
The development of nanoscale systems capable to perform specific functions under external control is...
Azobenzene undergoes reversible cis↔ trans photoisomerization upon irradiation. Substituents often c...
Certain molecules (photochromic compounds), when exposed to the light of a specific wavelength, unde...
The photoisomerization of azobenzene has been studied at room temperature in ethanol and P. Me.H., a...
ABSTRACT: Azobenzene functionalized with ortho-fluo-rine atoms has a lower energy of the n-orbital o...
Here we report a photochemical and kinetic study of the thermal relaxation reaction of a double azob...
The photo-induced trans–cis isomerization of the azobenzene derivative 4-nitro-4'-(dimethylamino)azo...
International audienceAzobenzene molecular switches can interconvert both photochemically and therma...
none6noShape-persistent azobenzene tetramers functionalized at the periphery with alkyloxy substitue...
The rates of Z-E isomerization of azobenzene and seven 4-substituted derivatives (CH3, CF3, OCH3, n-...
The E-Z photoisomerization of azobenzene - owing to its high efficiency, excellent reversibility and...
2,2'-Dihydroxyazobenzene (DAB), 2,2'-azotoluene (AT) and azobenzene (AB) were isolated in argon and ...
The influence of substituents and media polarity on the photoinducedE→Z geometrical isomerisation of...
The development of nanoscale systems capable to perform specific functions under external control is...
Azobenzene undergoes reversible cis↔ trans photoisomerization upon irradiation. Substituents often c...
Certain molecules (photochromic compounds), when exposed to the light of a specific wavelength, unde...
The photoisomerization of azobenzene has been studied at room temperature in ethanol and P. Me.H., a...
ABSTRACT: Azobenzene functionalized with ortho-fluo-rine atoms has a lower energy of the n-orbital o...
Here we report a photochemical and kinetic study of the thermal relaxation reaction of a double azob...
The photo-induced trans–cis isomerization of the azobenzene derivative 4-nitro-4'-(dimethylamino)azo...