H- Opacity and Water Dissociation in the Dayside Atmosphere of the Very Hot Gas Giant WASP-18b

We present one of the most precise emission spectra of an exoplanet observed so far. We combine five secondary eclipses of the hot Jupiter WASP-18b (T day ~ 2900 K) that we secured between 1.1 and 1.7 μm with the Wide Field Camera 3 instrument on board the Hubble Space Telescope. Our extracted spectrum (S/N = 50, R ~ 40) does not exhibit clearly identifiable molecular features but is poorly matched by a blackbody spectrum. We complement this data with previously published Spitzer/Infrared Array Camera observations of this target and interpret the combined spectrum by computing a grid of self-consistent, 1Dforward models, varying the composition and energy budget. At these hightemperatures, we find there are important contributions to the overall opacity from H− ions, as well as the removal of major molecules by thermal dissociation (including water), and thermal ionization of metals. These effects were omitted in previous spectral retrievals for very hot gas giants, and we argue that they must be included to properly interpret the spectra of these objects. We infer a new metallicity and C/O ratio for WASP-18b, and find them well constrained to be solar ([M/H] = −0.01 ± 0.35, C/O