The catalytic properties of gold nanoparticles are determined by their electronic and geometric structures. We revealed the geometries of several small neutral gold clusters in the gas phase by using vibrational spectroscopy between 47 and 220 wavenumbers. A two- dimensional structure for neutral Au-7 and a pyramidal structure for neutral Au-20 can be unambiguously assigned. The reduction of the symmetry when a corner atom is cut from the tetrahedral Au-20 cluster is directly reflected in the vibrational spectrum of Au-19
Gold nanoparticles and sub-nanoparticles famously act as highly efficient and selective low-temperat...
The aim of the current study is to explore the structural evolution of neutral and negatively charge...
The 20-nanogold cluster Au-20 exhibits a large variety of two- and three-dimensional isomeric forms....
The catalytic properties of gold nanoparticles are determined by their electronic and geometric stru...
Vibrational spectra of small neutral gold clusters containing up to 8 Au atoms are measured in the f...
Vibrational spectra of small neutral gold clusters containing up to 8 Au atoms are measured in the f...
Since gold clusters have mostly been studied theoretically by using DFT calculations, more accurate ...
old is the most inert metal in the periodic table. However, at nano-meter scale, supported gold par-...
Free bare gold clusters in the size range from few tens to few hundred atoms (≤1 nm dimensions) have...
We present an experimental and theoretical study of the structure of small, neutral gold clusters—Au...
Determining geometric and electronic structures of gold nanoparticles are of fundamental interest in...
The free-standing Au20 cluster has a unique tetrahedral shape and a large HOMO-LUMO (highest occupie...
Gold nanoparticles and sub-nanoparticles famously act as highly efficient and selective low-temperat...
The geometric and electronic structure of the Au₆Y⁺ cation is studied by gas phase vibrational spect...
We present an experimental and theoretical study of the structure of small, neutral gold clusters\u2...
Gold nanoparticles and sub-nanoparticles famously act as highly efficient and selective low-temperat...
The aim of the current study is to explore the structural evolution of neutral and negatively charge...
The 20-nanogold cluster Au-20 exhibits a large variety of two- and three-dimensional isomeric forms....
The catalytic properties of gold nanoparticles are determined by their electronic and geometric stru...
Vibrational spectra of small neutral gold clusters containing up to 8 Au atoms are measured in the f...
Vibrational spectra of small neutral gold clusters containing up to 8 Au atoms are measured in the f...
Since gold clusters have mostly been studied theoretically by using DFT calculations, more accurate ...
old is the most inert metal in the periodic table. However, at nano-meter scale, supported gold par-...
Free bare gold clusters in the size range from few tens to few hundred atoms (≤1 nm dimensions) have...
We present an experimental and theoretical study of the structure of small, neutral gold clusters—Au...
Determining geometric and electronic structures of gold nanoparticles are of fundamental interest in...
The free-standing Au20 cluster has a unique tetrahedral shape and a large HOMO-LUMO (highest occupie...
Gold nanoparticles and sub-nanoparticles famously act as highly efficient and selective low-temperat...
The geometric and electronic structure of the Au₆Y⁺ cation is studied by gas phase vibrational spect...
We present an experimental and theoretical study of the structure of small, neutral gold clusters\u2...
Gold nanoparticles and sub-nanoparticles famously act as highly efficient and selective low-temperat...
The aim of the current study is to explore the structural evolution of neutral and negatively charge...
The 20-nanogold cluster Au-20 exhibits a large variety of two- and three-dimensional isomeric forms....