Fluoropolymer studies for radiation dosymetry

The polymers Tetrafluoroethylene- hexa- fluoropropylene (FEP) and Tetrafluoroethylene- per- fluoromethoxyethelene (PFA) are normally used as anti-adherent coatings and can also be applied for several applications in research. For example, they can be used as radiation dosimeters for X-ray and gamma photons, electrons, protons and other ionazing particles. In order to determine radiation induced damage, that can compromise applications in dosimetry, FEP and PFA films were bombarded with protons of 1 MeV at fluences from 1 × 10(11) protons/cm² to 1 × 10(16) protons/cm². During the bombardment, the chemical species emission was monitored with a Residual Gas Analyzer (RGA), and results show that the CF3 radical is the specie preferentially emitted. The bombarded films were also analyzed with Optical Absorption Photospectrometry (OAP) which shows quantitative chemically specific evidence of the damage caused by the proton bombardment. Our results show that damage to polymers is detectable for all fluences used in this work, but damage that can compromise applications in dosimetry occurs only for fluences greater than 1 × 10(14) protons/cm²