Add to ORKGA strong metal support interaction (SMSI) effect was observed on Pd/Nb2O5 and Pd/TiO2 catalysts, and it produces small, exposed Pd ensembles. A decrease in the trans/cis 2-butene ratio was observed after reduction at 773 K. Selectivity changes were ascribed to the decoration model. Theoretical models were developed based on semi-empirical molecular-orbital calculations for 1,3-butadiene and Pd n clusters. Experimental results are in agreement with our theoretical model, which proposes a greater stabilization of the cisoid intermediate on small Pd ensembles
Two types of commercial carbon nanofibers with different graphitic structure, Pyrograph PR24-HHT (NF...
Results were repeatedly obtained that were consistent with a hypothesis proposed at the beginning of...
The role of the support in the gas phase hydrogenation of butyronitrile over Pd/Al2O3 and Pd/C (2.5–...
The selective hydrogenation of 1,3-butadiene in the presence of n-butenes over supported palladium c...
The selective hydrogenation of 1,3-butadiene on Pd(111) and Pd(110) model catalysts was studied at a...
174-176Bond order conservation-Morse potential model (BOC-MP) has been used to study the 1,3-butadie...
The selective hydrogenation of 1,3-butadiene on Pd(111) and Pd(110) model catalysts was studied at a...
The partial hydrogenation of 1,3-butadiene (13BD) to several C4H8 products, including 1-butene (1B),...
Modifications to the selectivity during partial hydrogenation of butadiene over graphite supported P...
The production of cis-2-butene (cis-2B) on Pd/Ni(1 1 1) bimetallic model was evaluated considering t...
Hydrogenation of 1,3-butadiene over supported Pt particles has long been known as a structure sensit...
Hydrogenation of 1,3-butadiene over supported Pt particles has long been known as a structure sensit...
Copper addition to palladium increases both activity and selectivity in the selective hydrogenation ...
Hydrogenation of unsaturated hydrocarbon compounds, catalyzed by transition metals, is traditionally...
Hydrogenation of unsaturated hydrocarbon compounds, catalyzed by transition metals, is traditionally...
Two types of commercial carbon nanofibers with different graphitic structure, Pyrograph PR24-HHT (NF...
Results were repeatedly obtained that were consistent with a hypothesis proposed at the beginning of...
The role of the support in the gas phase hydrogenation of butyronitrile over Pd/Al2O3 and Pd/C (2.5–...
The selective hydrogenation of 1,3-butadiene in the presence of n-butenes over supported palladium c...
The selective hydrogenation of 1,3-butadiene on Pd(111) and Pd(110) model catalysts was studied at a...
174-176Bond order conservation-Morse potential model (BOC-MP) has been used to study the 1,3-butadie...
The selective hydrogenation of 1,3-butadiene on Pd(111) and Pd(110) model catalysts was studied at a...
The partial hydrogenation of 1,3-butadiene (13BD) to several C4H8 products, including 1-butene (1B),...
Modifications to the selectivity during partial hydrogenation of butadiene over graphite supported P...
The production of cis-2-butene (cis-2B) on Pd/Ni(1 1 1) bimetallic model was evaluated considering t...
Hydrogenation of 1,3-butadiene over supported Pt particles has long been known as a structure sensit...
Hydrogenation of 1,3-butadiene over supported Pt particles has long been known as a structure sensit...
Copper addition to palladium increases both activity and selectivity in the selective hydrogenation ...
Hydrogenation of unsaturated hydrocarbon compounds, catalyzed by transition metals, is traditionally...
Hydrogenation of unsaturated hydrocarbon compounds, catalyzed by transition metals, is traditionally...
Two types of commercial carbon nanofibers with different graphitic structure, Pyrograph PR24-HHT (NF...
Results were repeatedly obtained that were consistent with a hypothesis proposed at the beginning of...
The role of the support in the gas phase hydrogenation of butyronitrile over Pd/Al2O3 and Pd/C (2.5–...