Add to ORKGA mathematical model for prediction of monomer conversion, of particle number and of the evolution of the particle size distribution (PSD) in dispersion polymerization is developed. Despite being completed very early during the polymerization process (monomer conversion <1%), nucleation of new particles is the most important factor affecting the PSD. In order to describe the particle nucleation phenomena, the mechanism of homogeneous coagulative nucleation is considered. According to this mechanism, polymer chain aggregates can either coagulate and grow, to give birth to new polymer particles (particle nucleation), or be captured by existing polymer particles. Two sets of population balance equations are used: one for the aggregates, and a ...
The objective of the present paper is to demonstrate that the explicit radical-particle size distrib...
The objective of the present paper is to demonstrate that the explicit radical-particle size distrib...
A model for evaluating the instantaneous degree of polymerization distribution of homopolymers produ...
A detailed mathematical model for styrene free radical polymerization system based on the multigrai...
An extensive model is given for the particle size distribution (PSD), particle number, particle size...
The development of concentration gradients in the seeded emulsion homopolymerization of styrene has ...
ABSTRACT: A detailed mathematical model for styrene free radical polymerization system based on the ...
Suspension polymerisation processes are commercially important for the production of polymer beads h...
A detailed theory is presented for nucleation kinetics in emulsion polymerization systems based on t...
A review of the use and limitations of Population Balance Equations (PBE) in the modeling of emulsio...
Suspension polymerisation processes are commercially important for the production of polymer beads h...
A detailed dynamic model was developed for a styrene emulsion polymerisation semi-batch reactor to p...
A detailed mathematical model for particle size distribution in continuous emulsion polymerization o...
The traditional theoretical approach to emulsion polymerization is extended to include effects due t...
Three different models are developed to calculate the thermodynamic product size distribution in a n...
The objective of the present paper is to demonstrate that the explicit radical-particle size distrib...
The objective of the present paper is to demonstrate that the explicit radical-particle size distrib...
A model for evaluating the instantaneous degree of polymerization distribution of homopolymers produ...
A detailed mathematical model for styrene free radical polymerization system based on the multigrai...
An extensive model is given for the particle size distribution (PSD), particle number, particle size...
The development of concentration gradients in the seeded emulsion homopolymerization of styrene has ...
ABSTRACT: A detailed mathematical model for styrene free radical polymerization system based on the ...
Suspension polymerisation processes are commercially important for the production of polymer beads h...
A detailed theory is presented for nucleation kinetics in emulsion polymerization systems based on t...
A review of the use and limitations of Population Balance Equations (PBE) in the modeling of emulsio...
Suspension polymerisation processes are commercially important for the production of polymer beads h...
A detailed dynamic model was developed for a styrene emulsion polymerisation semi-batch reactor to p...
A detailed mathematical model for particle size distribution in continuous emulsion polymerization o...
The traditional theoretical approach to emulsion polymerization is extended to include effects due t...
Three different models are developed to calculate the thermodynamic product size distribution in a n...
The objective of the present paper is to demonstrate that the explicit radical-particle size distrib...
The objective of the present paper is to demonstrate that the explicit radical-particle size distrib...
A model for evaluating the instantaneous degree of polymerization distribution of homopolymers produ...