Local structural properties of 0.5BiMnO(3)-0.5ATiO(3) (A = Ba or Sr)

Norberg, Stefan
Hull, S.
Mathieu, R.
Eriksson, Sten

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Publication date

January 2010

DOI

10.1039/b912519a

Publisher

Royal Society of Chemistry (RSC)

Abstract

Neutron total scattering data have been used to probe the long-and short-range structure of 0.5BiMnO(3)-0.5ATiO(3) (A = Ba or Sr). Modelling of the total scattering data, using the reverse Monte Carlo (RMC) method, reveals local disorder that differs substantially from the average structure. Significantly, the Bi3+ cations prefer to adopt an asymmetric coordination due to the influence of the lone-pair electrons

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Local structural properties of 0.5BiMnO(3)-0.5ATiO(3) (A = Ba or Sr)

Abstract

Extracted data

Local structural properties of 0.5BiMnO(3)-0.5ATiO(3) (A = Ba or Sr)

Abstract

Extracted data

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