Add to ORKG1. The change in the valence state of the phosphorus atom influences the orientation with respect to the P-O(Ph) bond in 2-phenoxy-2-oxo(thiono)-1,3,2-dioxaphosphorinanes. 2. An orthogonal conformation is realized in the O-Ph fragment of the compounds investigated, regardless of the hybridization of the phosphorus. © 1980 Plenum Publishing Corporation
1. 2-X-4,5,6,7-Dibenzo-1,3,2-dioxaphosphenanes (X=Cl, OEt, OPh) have a twist form, and angle of twis...
1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs w...
Using PMR spectroscopy and the dipole moment and Kerr effect methods it has been shown that 2-methox...
1. The change in the valence state of the phosphorus atom influences the orientation with respect to...
1. For 2-dialkylamino-2-thiono-1,3,2-dioxaphosphorinanes, the preferred conformation is the cross wi...
1. A determination has been made of the dipole moments of the phosphoryl group in the axial and equa...
1. 2-Aroxy-2-oxo-1,3,2-oxaselenaphosphorinanes have primarily a chair conformation with an axial ori...
1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-d...
According to the data from the1H NMR spectra, the dipole moments, and the Kerr effect, the preferred...
1. Polarization and polarizability parameters have been determined for phosphoryl bonds in axial and...
1. In solution, 5,5-bis(bromomethyl)-1,3,2-dioxaphosphorinane exists as an equilibrium mixture of co...
A chair conformation with an axial orientation of the phosphoryl or thiophosphoryl group is preferab...
1. On the basis of IR and Raman vibrational spectra,1H NMR spectra, and measurements of dipole momen...
1. The geometric isomers of the corresponding tetra-coordinated phosphorus derivatives were obtained...
1. The dipole moments and Kerr constants of five 3-methoxy- and 3-phenoxy-l-thia-3-phosphethanes wit...
1. 2-X-4,5,6,7-Dibenzo-1,3,2-dioxaphosphenanes (X=Cl, OEt, OPh) have a twist form, and angle of twis...
1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs w...
Using PMR spectroscopy and the dipole moment and Kerr effect methods it has been shown that 2-methox...
1. The change in the valence state of the phosphorus atom influences the orientation with respect to...
1. For 2-dialkylamino-2-thiono-1,3,2-dioxaphosphorinanes, the preferred conformation is the cross wi...
1. A determination has been made of the dipole moments of the phosphoryl group in the axial and equa...
1. 2-Aroxy-2-oxo-1,3,2-oxaselenaphosphorinanes have primarily a chair conformation with an axial ori...
1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-d...
According to the data from the1H NMR spectra, the dipole moments, and the Kerr effect, the preferred...
1. Polarization and polarizability parameters have been determined for phosphoryl bonds in axial and...
1. In solution, 5,5-bis(bromomethyl)-1,3,2-dioxaphosphorinane exists as an equilibrium mixture of co...
A chair conformation with an axial orientation of the phosphoryl or thiophosphoryl group is preferab...
1. On the basis of IR and Raman vibrational spectra,1H NMR spectra, and measurements of dipole momen...
1. The geometric isomers of the corresponding tetra-coordinated phosphorus derivatives were obtained...
1. The dipole moments and Kerr constants of five 3-methoxy- and 3-phenoxy-l-thia-3-phosphethanes wit...
1. 2-X-4,5,6,7-Dibenzo-1,3,2-dioxaphosphenanes (X=Cl, OEt, OPh) have a twist form, and angle of twis...
1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs w...
Using PMR spectroscopy and the dipole moment and Kerr effect methods it has been shown that 2-methox...