Add to ORKG1. The aryl group is rotated by an angle of 65-75° with respect to the C-S-C plane in the aryl vinyl sulfones and their β-chloroderivatives containing H, CH3, CL, and Br substituents; in nitrophenyl vinyl sulfone, the rotation is 4-28°. 2. The unsaturated group inthe aryl vinyl sulfones, aryl trans-β-chlorovinyl sulfones, and the aryl trans-β-chlorovinyl sulfides have s-trans conformation, or something close thereto, displacement out of the C-S-C plane being as high as 40°. © 1977 Plenum Publishing CorporationPlenum Publishing Corporation
1. The anisotropy of the polarizability of the {Mathematical expression} bond was determined. 2. The...
In solution, the arylmethanesulfonates exist as two conformers with the methyl and aryl radicals in ...
1. Molecules of arylvinyl selenides have a maximally conjugated planar s-trans structure, 2. The con...
1. The aryl group is rotated by an angle of 65-75° with respect to the C-S-C plane in the aryl vinyl...
The conformations of the arylmethylsulfones in solution are such that the plane of the aromatic ring...
1. The substituted methylarylsulfonates and arylarylsulfonates exist as mixtures of trans and gauche...
1. Dipole moments and components of the poiarizability tensor have been calculated for the S-N bond ...
Aryl is in a skewed position (φ{symbol}=73±13‡) in tert-butyl aryl sulfones. There are no significan...
1. Conformational equilibrium between the gauche- and trans-forms is attained in α-halogenated sulfo...
1. Aryl methyl sulfoxides have a conformation close to an overlapping location of the S-O bond and t...
1. Certain 2-(4-pyridyl)ethyl aryl selenides and 2-(4-pyridyl)ethyl aryl sulfones have been synthesi...
The X-rays structures of diphenyl sulfone 1, bis(3-aminophenyl) sulfone 2, bis(4-nitrophenyl) sulfon...
1. Each of the aryl methyl disulfides exists in skew conformation with a C-S-S-C dihedral angle of 7...
1. The anisotropy of the polarizability of the {Mathematical expression} bond was determined. 2. The...
In solution, the arylmethanesulfonates exist as two conformers with the methyl and aryl radicals in ...
1. Molecules of arylvinyl selenides have a maximally conjugated planar s-trans structure, 2. The con...
1. The aryl group is rotated by an angle of 65-75° with respect to the C-S-C plane in the aryl vinyl...
The conformations of the arylmethylsulfones in solution are such that the plane of the aromatic ring...
1. The substituted methylarylsulfonates and arylarylsulfonates exist as mixtures of trans and gauche...
1. Dipole moments and components of the poiarizability tensor have been calculated for the S-N bond ...
Aryl is in a skewed position (φ{symbol}=73±13‡) in tert-butyl aryl sulfones. There are no significan...
1. Conformational equilibrium between the gauche- and trans-forms is attained in α-halogenated sulfo...
1. Aryl methyl sulfoxides have a conformation close to an overlapping location of the S-O bond and t...
1. Certain 2-(4-pyridyl)ethyl aryl selenides and 2-(4-pyridyl)ethyl aryl sulfones have been synthesi...
The X-rays structures of diphenyl sulfone 1, bis(3-aminophenyl) sulfone 2, bis(4-nitrophenyl) sulfon...
1. Each of the aryl methyl disulfides exists in skew conformation with a C-S-S-C dihedral angle of 7...
1. The anisotropy of the polarizability of the {Mathematical expression} bond was determined. 2. The...
In solution, the arylmethanesulfonates exist as two conformers with the methyl and aryl radicals in ...
1. Molecules of arylvinyl selenides have a maximally conjugated planar s-trans structure, 2. The con...