Two-dimensional NMR spectroscopy was used to establish that the chair ⇄ chair-inversion process in 2,2-dimethyl-1,3-dithiepin and its 5,6-benz derivative is a function of transitions between intermediate boat and twist structures, while the role of direct chair ⇄ chair transitions is small. © 1990 Plenum Publishing Corporation
Raman spectroscopy has been applied to the title compounds; dithiaketals of acetone, methyl-ethylket...
By means of dynamic13C NMR, spectra have been obtained for the "frozen" chair and twist conformers o...
1. Unsubstituted 2-dialkylamino-1,3,2-dioxaphosphorinanes with three- and four-coordinated phosphoru...
Two-dimensional NMR spectroscopy was used to establish that the chair ⇄ chair-inversion process in 2...
From an analysis of the variation of1 H NMR spectra with temperature it has been shown that 2-substi...
A procedure was developed for determination of the number of components (two or more than two) parti...
In the case of three isomers (α, Β, and γ) of 1-ethyl-2,5-dimethyl-4-phenyl-4-piperidinol it is show...
X-ray structure investigation of the title compounds displays a chair form with equatorial alkyl sub...
According to dynamic 13C NMR spectroscopy trans-2-R-(R=Ph, Me, Et, Pri)-5,6-benzocycloheptene-1-oxid...
1H NMR spectroscopy, measurements of dipole moments, and the Kerr effect have been used to study the...
Using vibrational spectroscopy methods in different aggregate states and solutions with variation of...
4,4,7,7-tetramethyl-1,3-dioxepane and 2,2,4,4,7,7-hexamethyl-2-sila-1,3-dioxepane exist in solution ...
In conformity with the data of1H NMR, DM, and the Kerr effect for 2-dialkylamino-2-oxo(thiono, selen...
Based on the data of the method of dipole moments and NMR spectroscopy, 2,4,6-trimethyl-1, 3, 5-diox...
13C NMR γ-anti effect data versus dihedral angle RCXC (X=O, S; R=Me, Ph, t-Bu) in a series of six ei...
Raman spectroscopy has been applied to the title compounds; dithiaketals of acetone, methyl-ethylket...
By means of dynamic13C NMR, spectra have been obtained for the "frozen" chair and twist conformers o...
1. Unsubstituted 2-dialkylamino-1,3,2-dioxaphosphorinanes with three- and four-coordinated phosphoru...
Two-dimensional NMR spectroscopy was used to establish that the chair ⇄ chair-inversion process in 2...
From an analysis of the variation of1 H NMR spectra with temperature it has been shown that 2-substi...
A procedure was developed for determination of the number of components (two or more than two) parti...
In the case of three isomers (α, Β, and γ) of 1-ethyl-2,5-dimethyl-4-phenyl-4-piperidinol it is show...
X-ray structure investigation of the title compounds displays a chair form with equatorial alkyl sub...
According to dynamic 13C NMR spectroscopy trans-2-R-(R=Ph, Me, Et, Pri)-5,6-benzocycloheptene-1-oxid...
1H NMR spectroscopy, measurements of dipole moments, and the Kerr effect have been used to study the...
Using vibrational spectroscopy methods in different aggregate states and solutions with variation of...
4,4,7,7-tetramethyl-1,3-dioxepane and 2,2,4,4,7,7-hexamethyl-2-sila-1,3-dioxepane exist in solution ...
In conformity with the data of1H NMR, DM, and the Kerr effect for 2-dialkylamino-2-oxo(thiono, selen...
Based on the data of the method of dipole moments and NMR spectroscopy, 2,4,6-trimethyl-1, 3, 5-diox...
13C NMR γ-anti effect data versus dihedral angle RCXC (X=O, S; R=Me, Ph, t-Bu) in a series of six ei...
Raman spectroscopy has been applied to the title compounds; dithiaketals of acetone, methyl-ethylket...
By means of dynamic13C NMR, spectra have been obtained for the "frozen" chair and twist conformers o...
1. Unsubstituted 2-dialkylamino-1,3,2-dioxaphosphorinanes with three- and four-coordinated phosphoru...