Add to ORKGThe enthalpy and entropy of activation of the chair(e)-boat(e) interconversion for 2-substituted 1,3-dithia-5,6-benzocycloheptenes depend significantly on the type of the solvent, whereby the changes in the enthalpy of equilibrium and of activation are not determined by the same factors when the solvent is changed. © 1989 Plenum Publishing Corporation
Abstract: The solvent effects on the rate constants and activation parameters of several intermolecu...
1. The position of equilibrium of 4-carbomethoxy-1, 3-dithiacyclohexanone-5 (I), 2-methyl-4-carbomet...
The solvent dependence of thermodynamic parameters of conformational equilibria in trans-1,2-dichlor...
The enthalpy and entropy of activation of the chair(e)-boat(e) interconversion for 2-substituted 1,3...
From an analysis of the variation of1 H NMR spectra with temperature it has been shown that 2-substi...
Medium effect on the conformational equilibrium of a model seven-membered trisulfide represented in ...
1. By graphic processing of the dipole moments of cis-2-aryl-4-R-1,3-dioxa-5,6-benzo-cycloheptenes r...
It has been shown that the observed differences in enthalpy and entropy between equilibrium states o...
The thermodynamic parameters of the conformational equilibrium for 3-substituted 2,4-dithia-3,5-dihy...
The dependences of the thermodynamic parameters of equilibria (Gibbs energies ΔG and enthalpies ΔH) ...
A new method was described for determining the enthalpy and entropy of the chair-chair equilibrium i...
1. By means of NMR, experimental data have been obtained on the dependence of conformational equilib...
Calorimetric measurements of transfer enthalpies associated with activity-coefficient determinations...
The conformational equilibrium of 1,2-dichloroethane (DCE) in 19 different media (vapour phase, liqu...
Motivation. Natural and synthetic benzophenones are compounds of great scientific and applied intere...
Abstract: The solvent effects on the rate constants and activation parameters of several intermolecu...
1. The position of equilibrium of 4-carbomethoxy-1, 3-dithiacyclohexanone-5 (I), 2-methyl-4-carbomet...
The solvent dependence of thermodynamic parameters of conformational equilibria in trans-1,2-dichlor...
The enthalpy and entropy of activation of the chair(e)-boat(e) interconversion for 2-substituted 1,3...
From an analysis of the variation of1 H NMR spectra with temperature it has been shown that 2-substi...
Medium effect on the conformational equilibrium of a model seven-membered trisulfide represented in ...
1. By graphic processing of the dipole moments of cis-2-aryl-4-R-1,3-dioxa-5,6-benzo-cycloheptenes r...
It has been shown that the observed differences in enthalpy and entropy between equilibrium states o...
The thermodynamic parameters of the conformational equilibrium for 3-substituted 2,4-dithia-3,5-dihy...
The dependences of the thermodynamic parameters of equilibria (Gibbs energies ΔG and enthalpies ΔH) ...
A new method was described for determining the enthalpy and entropy of the chair-chair equilibrium i...
1. By means of NMR, experimental data have been obtained on the dependence of conformational equilib...
Calorimetric measurements of transfer enthalpies associated with activity-coefficient determinations...
The conformational equilibrium of 1,2-dichloroethane (DCE) in 19 different media (vapour phase, liqu...
Motivation. Natural and synthetic benzophenones are compounds of great scientific and applied intere...
Abstract: The solvent effects on the rate constants and activation parameters of several intermolecu...
1. The position of equilibrium of 4-carbomethoxy-1, 3-dithiacyclohexanone-5 (I), 2-methyl-4-carbomet...
The solvent dependence of thermodynamic parameters of conformational equilibria in trans-1,2-dichlor...