Based on the dipole moment data, either a cis or near-cis orientation of the phosphoryl and methyl groups, or of the thiophosphoryl and trimethylsilyl groups, is realized in the 2-oxo-2-methylthio- and the 2-thiono-2-trimethylsiloxy-4-methyl- and -4,5-dimethyl-1,3,2-dioxaphospholanes. © 1977 Plenum Publishing Corporation
The three-dimensional structure of a number of 2-thiono-1,3,2-dioxaphosphorinanes was studied by mea...
Conformational analysis of 1,3,2-dioxaphospholane-2-yl-2,2,2- trifluoroacetate and 4,5-benzo-1,3,2-d...
1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-d...
Based on the dipole moment data, either a cis or near-cis orientation of the phosphoryl and methyl g...
A chair conformation with an axial orientation of the phosphoryl or thiophosphoryl group is preferab...
1. We were the first to determine the group dipole moment of the 4,4,5,5-tetramethyl-2-oxo-1,3,2-dio...
Conformational analysis of 4-methyl-2-trimethylsiloxy-1,3,2- dioxaphosphinane was performed by the d...
1. A study has been made of the dipole moments, Kerr constants, and IR spectra of silicon-containing...
Using PMR spectroscopy and the dipole moment and Kerr effect methods it has been shown that 2-methox...
1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs w...
1. A determination has been made of the dipole moments of the phosphoryl group in the axial and equa...
The p-substituted benzyldiphenylphosphine oxides in solution have a conformation with a gauche orien...
Conformational analysis of 1,3,2-dioxaphospholan-2-yl 2,2,2- trifluoroacetate and 4,5-benzo-1,3,2-di...
The three-dimensional structure of a number of 2-thiono-1,3,2-dioxaphosphorinanes was studied by mea...
Conformational analysis of 1,3,2-dioxaphospholane-2-yl-2,2,2- trifluoroacetate and 4,5-benzo-1,3,2-d...
1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-d...
Based on the dipole moment data, either a cis or near-cis orientation of the phosphoryl and methyl g...
A chair conformation with an axial orientation of the phosphoryl or thiophosphoryl group is preferab...
1. We were the first to determine the group dipole moment of the 4,4,5,5-tetramethyl-2-oxo-1,3,2-dio...
Conformational analysis of 4-methyl-2-trimethylsiloxy-1,3,2- dioxaphosphinane was performed by the d...
1. A study has been made of the dipole moments, Kerr constants, and IR spectra of silicon-containing...
Using PMR spectroscopy and the dipole moment and Kerr effect methods it has been shown that 2-methox...
1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs w...
1. A determination has been made of the dipole moments of the phosphoryl group in the axial and equa...
The p-substituted benzyldiphenylphosphine oxides in solution have a conformation with a gauche orien...
Conformational analysis of 1,3,2-dioxaphospholan-2-yl 2,2,2- trifluoroacetate and 4,5-benzo-1,3,2-di...
The three-dimensional structure of a number of 2-thiono-1,3,2-dioxaphosphorinanes was studied by mea...
Conformational analysis of 1,3,2-dioxaphospholane-2-yl-2,2,2- trifluoroacetate and 4,5-benzo-1,3,2-d...
1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-d...