Add to ORKG1. The reaction of triethyl phosphite with 2,6-dibromocyclohexanone follows a complex course. In addition to the expected diethylphosphoric ester of the enol form of the ester of cyclohexanone-2-phosphonic-1 acid, by-products are formed which are produced by conversions of the latter compound (diethyl ester of cyclohexanone-2-phosphonic-1 acid and tetraethyl ester of hypophosphoric acid), and also an intermediate product, diethyl bromo-6-cyclohexen-1-yl phosphoric ester [diethylcyclohexadien-1,5-yl phosphate, diethyl phenyl phosphate]. 2. The cis- and trans-isomers of 2,6-dibromocyclohexanone react differently with triethyl phosphite. The trans-isomer gives the diethylphosphoric ester of the enol form of the ester of cyclohexanone-2-phospho...
1. The action of diethyl ethylphosphonite on chloroacetone results in the formation of ethyl isoprop...
1. The results reported point to an analogy between β-keto and β-alkoxycarbonyl derivatives of phosp...
1. The following alkylphosphonic esters have been synthesized: dibutyl, dihexyl, dioctyl, and didecy...
1. The reaction of triethyl phosphite with 2,6-dibromocyclohexanone follows a complex course. In add...
1. The reaction of trans-2,6-dibromocyclohexanone with one and two molecules of triethyl phosphite f...
1. On the basis of chemical and spectrographic data it was shown that the product of the action of s...
1. The reaction of 2,6-dibenzylidenecyclohexanone with trialkyl phosphites gave phosphoranes, and so...
1. According to chemical and spectroscopic data the product of the reaction of 2-bromoacetophenone w...
1. The reaction of 2-chlorocyclopentanone with triethyl phosphite leads to the formation of 1-cyclop...
The action of diethyl ethylphosphonite on α-chlorocyclohexanone gives cyclohexen-1-yl-1 -ethyl ethyl...
1. Reaction of triethyl phosphite with chloro- and bromo-acetones* and 1-bromo-2-butanone gives the ...
1. Triethyl and triisopropyl phosphites, when reacting with 2-furaldehyde and with benzaldehyde, are...
1. With the object of studying their tautomerism, the following compounds were synthesized for the f...
1. The action of diethyl ethylphosphonite on chloroacetone results in the formation of ethyl isoprop...
1. The results reported point to an analogy between β-keto and β-alkoxycarbonyl derivatives of phosp...
1. The following alkylphosphonic esters have been synthesized: dibutyl, dihexyl, dioctyl, and didecy...
1. The reaction of triethyl phosphite with 2,6-dibromocyclohexanone follows a complex course. In add...
1. The reaction of trans-2,6-dibromocyclohexanone with one and two molecules of triethyl phosphite f...
1. On the basis of chemical and spectrographic data it was shown that the product of the action of s...
1. The reaction of 2,6-dibenzylidenecyclohexanone with trialkyl phosphites gave phosphoranes, and so...
1. According to chemical and spectroscopic data the product of the reaction of 2-bromoacetophenone w...
1. The reaction of 2-chlorocyclopentanone with triethyl phosphite leads to the formation of 1-cyclop...
The action of diethyl ethylphosphonite on α-chlorocyclohexanone gives cyclohexen-1-yl-1 -ethyl ethyl...
1. Reaction of triethyl phosphite with chloro- and bromo-acetones* and 1-bromo-2-butanone gives the ...
1. Triethyl and triisopropyl phosphites, when reacting with 2-furaldehyde and with benzaldehyde, are...
1. With the object of studying their tautomerism, the following compounds were synthesized for the f...
1. The action of diethyl ethylphosphonite on chloroacetone results in the formation of ethyl isoprop...
1. The results reported point to an analogy between β-keto and β-alkoxycarbonyl derivatives of phosp...
1. The following alkylphosphonic esters have been synthesized: dibutyl, dihexyl, dioctyl, and didecy...