Add to ORKG1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-dioxaphosphorinanes and their phosphoryl and thiophosphoryl derivatives. 2. It has been established that the chair conformation with axial arrangement of the phenyl group is the preferred conformation in the 2-phenyl-5,5-dimethyl-1,3,2-dioxaphosphorinanes. The phosphoryl and thiophosphoryl analogs of the phosphorinanes exist as equilibrium mixtures of two chair forms, with the point of equilibrium shifted toward the conformer with equatorial arrangement of the phenyl group. © 1980 Plenum Publishing Corporation
The three-dimensional structure of a number of 2-thiono-1,3,2-dioxaphosphorinanes was studied by mea...
A chair conformation with an axial orientation of the phosphoryl or thiophosphoryl group is preferab...
1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs w...
1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-d...
1. A determination has been made of the dipole moments of the phosphoryl group in the axial and equa...
1. Polarization and polarizability parameters have been determined for phosphoryl bonds in axial and...
1. In solution, 5,5-bis(bromomethyl)-1,3,2-dioxaphosphorinane exists as an equilibrium mixture of co...
1. For 2-dialkylamino-2-thiono-1,3,2-dioxaphosphorinanes, the preferred conformation is the cross wi...
1. The change in the valence state of the phosphorus atom influences the orientation with respect to...
1. A determination has been made of the dipole moments of the 2-(p-X-phenoxy)-2-oxo-1,2-oxaphosphori...
The three-dimensional structure of a number of 2-thiono-1,3,2-dioxaphosphorinanes was studied by mea...
A chair conformation with an axial orientation of the phosphoryl or thiophosphoryl group is preferab...
1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs w...
1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-d...
1. A determination has been made of the dipole moments of the phosphoryl group in the axial and equa...
1. Polarization and polarizability parameters have been determined for phosphoryl bonds in axial and...
1. In solution, 5,5-bis(bromomethyl)-1,3,2-dioxaphosphorinane exists as an equilibrium mixture of co...
1. For 2-dialkylamino-2-thiono-1,3,2-dioxaphosphorinanes, the preferred conformation is the cross wi...
1. The change in the valence state of the phosphorus atom influences the orientation with respect to...
1. A determination has been made of the dipole moments of the 2-(p-X-phenoxy)-2-oxo-1,2-oxaphosphori...
The three-dimensional structure of a number of 2-thiono-1,3,2-dioxaphosphorinanes was studied by mea...
A chair conformation with an axial orientation of the phosphoryl or thiophosphoryl group is preferab...
1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs w...