Add to ORKG1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs with a tricoordinated phosphorus atom were determined. 2. A graphical method was proposed for the analysis of the data of the method of dipole moments of cyclic compounds. 3. In all the compounds studied, a chair conformation with axial (or diaxial for the spiro compound) arrangement of the alkoxy group with a gauche-orientation of the methoxyl and ethoxyl radicals and a cisorientation of the phenoxy group is realized. © 1974 Consultants Bureau
1. The dipole moments and Kerr constants of five 3-methoxy- and 3-phenoxy-l-thia-3-phosphethanes wit...
1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-d...
The dipole moments and molar Kerr constants of 2-chloro-5,5-dimethyl-2-chloro-, and 4-methyl-2-chlor...
1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs w...
1. The dipole moments of 2-diethylamino-1,3,2-dioxaphosphorinane, 3,9-bis-(N-diethylamino)-2,4,8,10-...
1. A determination has been made of the dipole moments of the phosphoryl group in the axial and equa...
1. A determination has been made of the dipole moments of the 2-(p-X-phenoxy)-2-oxo-1,2-oxaphosphori...
1. We were the first to determine the group dipole moment of the 4,4,5,5-tetramethyl-2-oxo-1,3,2-dio...
The three-dimensional structure of a number of 2-thiono-1,3,2-dioxaphosphorinanes was studied by mea...
1. The dipole moments and Kerr constants of five 3-methoxy- and 3-phenoxy-l-thia-3-phosphethanes wit...
1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-d...
The dipole moments and molar Kerr constants of 2-chloro-5,5-dimethyl-2-chloro-, and 4-methyl-2-chlor...
1. The dipole moment of 2-alkoxy- and 2-phenoxy-l, 3,2-dioxaphosphorinanes and their spiro analogs w...
1. The dipole moments of 2-diethylamino-1,3,2-dioxaphosphorinane, 3,9-bis-(N-diethylamino)-2,4,8,10-...
1. A determination has been made of the dipole moments of the phosphoryl group in the axial and equa...
1. A determination has been made of the dipole moments of the 2-(p-X-phenoxy)-2-oxo-1,2-oxaphosphori...
1. We were the first to determine the group dipole moment of the 4,4,5,5-tetramethyl-2-oxo-1,3,2-dio...
The three-dimensional structure of a number of 2-thiono-1,3,2-dioxaphosphorinanes was studied by mea...
1. The dipole moments and Kerr constants of five 3-methoxy- and 3-phenoxy-l-thia-3-phosphethanes wit...
1. Bond polarity parameters have been determined for the phosphorus in 2-phenyl-5,5-dimethyl-1,3,2-d...
The dipole moments and molar Kerr constants of 2-chloro-5,5-dimethyl-2-chloro-, and 4-methyl-2-chlor...