Separation of acetylene from carbon dioxide and ethylene is challenging in view of their similar sizes and physical properties. Metal-organic frameworks (MOFs) in general are strong candidates for these separations owing to the presence of functional pore surfaces that can selectively capture a specific target molecule. Here, we report a novel 3D microporous cationic framework named JCM-1. This structure possesses imidazolium functional groups on the pore surfaces and pyrazolate as a metal binding group, which is well known to form strong metal-to-ligand bonds. The selective sorption of acetylene over carbon dioxide and ethylene in JCM-1 was successfully demonstrated by equilibrium gas adsorption analysis as well as dynamic breakthrough mea...
As a new type of porous material, metal organic frameworks (MOFs) have been widely studied in gas ad...
Recently, methanol-to-olefins (MTO) technology has been widely used. The development of new adsorben...
A novel three-dimensional microporous metal-organic framework Zn<SUB>4</SUB>L(DMA)<SUB>4 </SUB>(UTSA...
Separation of acetylene from carbon dioxide and ethylene is challenging in view of their similar siz...
The separation of acetylene, ethylene, and carbon dioxide is a great challenge in view of their simi...
The removal of acetylene from ethylene/acetylene mixtures containing 1% acetylene is a technological...
Selective-adsorption separation is an energy-efficient technology for the capture of acetylene (C2H2...
Separating acetylene from light hydrocarbon mixtures like ethylene is a very important process for d...
Acetylene separation is a very important but challenging industrial separation task. Here, through t...
A new three-dimensional microporous metal-organic framework, Cu-2(MFDI) (ZJU-60, H4MFDI = 5,5'-(9,9-...
Acetylene separation is a very important but challenging industrial separation task. Here, through t...
The realization of porous materials for highly selective separation of acetylene (C2H2) from various...
Herein we construct a novel three-dimension (3D) hydrogen-bonded organic framework (PFC-2) with a hi...
Porous materials that can undergo pore‐structure adjustment to better accommodate specific molecules...
The removal of acetylene from ethylene/acetylene mixtures containing 1% acetylene is a technological...
As a new type of porous material, metal organic frameworks (MOFs) have been widely studied in gas ad...
Recently, methanol-to-olefins (MTO) technology has been widely used. The development of new adsorben...
A novel three-dimensional microporous metal-organic framework Zn<SUB>4</SUB>L(DMA)<SUB>4 </SUB>(UTSA...
Separation of acetylene from carbon dioxide and ethylene is challenging in view of their similar siz...
The separation of acetylene, ethylene, and carbon dioxide is a great challenge in view of their simi...
The removal of acetylene from ethylene/acetylene mixtures containing 1% acetylene is a technological...
Selective-adsorption separation is an energy-efficient technology for the capture of acetylene (C2H2...
Separating acetylene from light hydrocarbon mixtures like ethylene is a very important process for d...
Acetylene separation is a very important but challenging industrial separation task. Here, through t...
A new three-dimensional microporous metal-organic framework, Cu-2(MFDI) (ZJU-60, H4MFDI = 5,5'-(9,9-...
Acetylene separation is a very important but challenging industrial separation task. Here, through t...
The realization of porous materials for highly selective separation of acetylene (C2H2) from various...
Herein we construct a novel three-dimension (3D) hydrogen-bonded organic framework (PFC-2) with a hi...
Porous materials that can undergo pore‐structure adjustment to better accommodate specific molecules...
The removal of acetylene from ethylene/acetylene mixtures containing 1% acetylene is a technological...
As a new type of porous material, metal organic frameworks (MOFs) have been widely studied in gas ad...
Recently, methanol-to-olefins (MTO) technology has been widely used. The development of new adsorben...
A novel three-dimensional microporous metal-organic framework Zn<SUB>4</SUB>L(DMA)<SUB>4 </SUB>(UTSA...