Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion

Baker, M.
Brown, David
Hesler, V.
Skelton, B.
White, A.

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Publication date

January 2007

DOI

10.1021/om0610546

Publisher

American Chemical Society (ACS)

ISSN

0276-7333

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Abstract

The formation of a cyclophane-NHC complex of Pd-(II) Via oxidatiVe addition of a C-C bond in a bridged biimidazolium ion to Pd(0) is described. The actiVe Pd(0) species appears to be [Pd(PPh3)2Br]-. Simple (unbridged) biimidazolium ions do not form NHC complexes under similar conditions

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Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion

Abstract

Extracted data

Synthesis of a Bis(NHC)Pd complex via oxidative addition of a C-C bond in a biimidazolium ion

Abstract

Extracted data

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