Synthesis and Characterization of Stable Phosphorus Carbabetaines

Phosphorus 1,3- and 1,4-carbabetaines with ′P(+)−C−C(−)′ and ′P(+)−C−C−C(−)′ structures, respectively, in which the carbanion moiety was significantly stabilized by two trifluoromethylsulfonyl groups, have been synthesized and characterized. Analysis of their X-ray crystal structures revealed that any attractive interactions between the anionic and cationic moieties were negligibly weak. This result was corroborated by using natural bond orbital (NBO) and Bader′s quantum theory of atoms in molecules (QTAIM) models. In contrast, performing the same analysis of a known 1,3-carbabetaine equivalent, which can be drawn as a ′P(+)−C−C=C−O(−)′ resonance structure, revealed pronounced charge-transfer interactions between the anionic and cationic moieties.This work was supported by a Grant-in-Aid for Scientific Research (C) from the Japan Society for the Promotion of Science (JSPS; 17K08224), the Hoansha Foundation, and the Spanish Ministry of Economy and Competitiveness (MINECO; CTQ2015- 65060-C2-1-P, CTQ2015-65060-C2-2-P, and a Predoctoral Contract for PhD Students to C.L.-M.). We thank Professor Simon Grabowsky (Universit-t Bremen) for his helpful discussions.Peer Reviewe