New particle formation: nucleation rates and spatial scales in the clean marine coastal environment

Nucleation of new, ultra-fine, aerosol particles has been observed in the clean marine coastal atmosphere under a variety of conditions. These nucleation events were observed to occur frequently over spatial scales of 10\u27s-100\u27s of metres and temporal scales of seconds to minutes. Two conditions appeared to be necessary for nucleation event to occur: low tide and solar irradiation. The requirement of low tide conditions suggests that the exposed shore area provides the source of new particle precursors. It is speculated that VOC and/or alkyl halide derivatives contribute to nucleation under these conditions. Nucleation rates were calculated to be approximate to 10(3) -10(4) cm(-3) s(-1), suggesting that the coastal zone is an important source of atmospheric nuclei