Improved Thermal Transfer Efficiency for Planar Solar Thermophotovoltaic Devices

Solar thermophotovoltaic (STPV) devices provide conversion of solar energy to electrical energy through the use of an intermediate absorber/emitter module, which converts the broad solar spectrum to a tailored spectrum that is emitted towards a photovoltaic cell. While the use of an absorber/emitter device could potentially overcome the Shockley-Queisser limit of photovoltaic conversion, it also increases the number of heat loss mechanisms. One of the most prohibitive aspects of STPV conversion is the thermal transfer efficiency, which is a measure of how well solar energy is delivered to the emitter. Although reported thermophotovoltaic efficiencies (thermal to electric) have exceeded 10%, previously measured STPV conversion efficiencies are below 1%. In this work, we present the design and characterization of a nanostructured absorber for use in a planar STPV device with a high emitter-to-absorber area ratio. We used a process for spatially-selective growth of vertically aligned multi-walled carbon nanotube (MWCNT) forests on highly reflective, smooth tungsten (W) surfaces. We implemented these MWCNT/W absorbers in a TPV system with a one-dimensional photonic crystal emitter, which was spectrally paired with a low bandgap PV cell. A high fidelity, system-level model of the radiative transfer in the device was experimentally validated and used to optimize the absorber surface geometry. For an operating temperature of approximately 1200 K, we experimentally demonstrated a 100% increase in overall STPV efficiency using a 4 to 1 emitter-to-absorber area ratio (relative to a 1 to 1 area ratio), due to improved thermal transfer efficiency. By further increasing the solar concentration incident on the absorber surface, increased emitter-to-absorber area ratios will improve both thermal transfer and overall efficiencies for these planar devices. Topics: Solar energyUnited States. Department of Energy. Office of Basic Energy Sciences (MIT S3TEC Energy Research Frontier Center of the Department of Energy. DE-FG02-09ER46577)MIT Energy Initiativ