Rydberg-state ionization dynamics and tunnel ionization rates in strong electric fields

Tunnel ionization rates of triplet Rydberg states in helium with principal quantum numbers close to 37 have been measured in electric fields at the classical ionization threshold of ∼ 197 V/cm. The measurements were performed in the time domain by combining high-resolution continuous-wave laser photoexcitation and pulsed electric field ionization. The observed tunnel ionization rates range from 10 5 to 10 7 s − 1 and have, together with the measured atomic energy-level structure in the corresponding electric fields, been compared to the results of calculations of the eigenvalues of the Hamiltonian matrix describing the atoms in the presence of the fields to which complex absorbing potentials have been introduced. The comparison of the measured tunnel ionization rates with the results of these, and additional calculations for hydrogenlike Rydberg states performed using semiempirical methods, have allowed the accuracy of these methods of calculation to be tested. For the particular eigenstates studied the measured ionization rates are ∼ 5 times larger than those obtained from semiempirical expression