Unexpected intermolecular aglycon transfer occurred in chemoselective glycosylations using glycosyl fluorides or trichloroacetimidates as glycosyl donors and partially protected thioglycosides as glycosyl acceptors. It is shown that this problem can be addressed by fine-tuning of the reactivity of the anomeric thioalkyl moiety and hydroxyl of the acceptor
Synthesis of stereochemically defined oligosaccharides by a series of glycosylation processes involv...
Mechanistic study of carbohydrate interactions in biological systems calls for the chemical synthesi...
Control of anomeric stereoselectivity in glycosylation with deoxofluorinated glycosyl donors is crit...
Unexpected intermolecular aglycon transfer occurred in chemoselective glycosylations using glycosyl ...
To probe the reaction mechanism, underlying the rearrangement of oft-used trichloroacetimidate glyco...
We describe in this paper the tuning effect of silyl protecting groups on the donor reactivity of ga...
The tuning effect of silyl protecting groups on the glycosylation reactivity of arabinofuranosyl phe...
The stereoselective synthesis of saccharide thioglycosides containing 1,2-<i>cis</i>-2-amino glycosi...
The acid-catalyzed reaction of 1,2-anhydro-3,4,6-tri-Obenzyl- R-D-glucopyranose (7) as glycosyl dono...
Stereoselective glycosylation remains the main challenge in the chemical synthesis of oligosaccharid...
The use of fully and partially <i>tert</i>-butyldimethylsilyl (TBDMS) protected fucose thioglycoside...
The development of selectively protected monosaccharide building blocks that can reliably be glycosy...
grantor: University of TorontoThe most commonly used method of stereoselective synthesis ...
A facile method to convert thioglycosides to glycosyl fluorides with Ipy2BF4 (py = pyridine) is pres...
International audienceA new method is described for building up anomeric glycosyl sulfoxides, via th...
Synthesis of stereochemically defined oligosaccharides by a series of glycosylation processes involv...
Mechanistic study of carbohydrate interactions in biological systems calls for the chemical synthesi...
Control of anomeric stereoselectivity in glycosylation with deoxofluorinated glycosyl donors is crit...
Unexpected intermolecular aglycon transfer occurred in chemoselective glycosylations using glycosyl ...
To probe the reaction mechanism, underlying the rearrangement of oft-used trichloroacetimidate glyco...
We describe in this paper the tuning effect of silyl protecting groups on the donor reactivity of ga...
The tuning effect of silyl protecting groups on the glycosylation reactivity of arabinofuranosyl phe...
The stereoselective synthesis of saccharide thioglycosides containing 1,2-<i>cis</i>-2-amino glycosi...
The acid-catalyzed reaction of 1,2-anhydro-3,4,6-tri-Obenzyl- R-D-glucopyranose (7) as glycosyl dono...
Stereoselective glycosylation remains the main challenge in the chemical synthesis of oligosaccharid...
The use of fully and partially <i>tert</i>-butyldimethylsilyl (TBDMS) protected fucose thioglycoside...
The development of selectively protected monosaccharide building blocks that can reliably be glycosy...
grantor: University of TorontoThe most commonly used method of stereoselective synthesis ...
A facile method to convert thioglycosides to glycosyl fluorides with Ipy2BF4 (py = pyridine) is pres...
International audienceA new method is described for building up anomeric glycosyl sulfoxides, via th...
Synthesis of stereochemically defined oligosaccharides by a series of glycosylation processes involv...
Mechanistic study of carbohydrate interactions in biological systems calls for the chemical synthesi...
Control of anomeric stereoselectivity in glycosylation with deoxofluorinated glycosyl donors is crit...
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