Photoenzymatic epoxidation of styrenes
- Schie, Van, Morten M.C.H.
- Paul, Caroline E.
- Arends, Isabel W.C.E.
- Hollmann, Frank
DOIAbstract
Two-component-diffusible-flavomonooxygenases are versatile biocatalysts for selective epoxidation-, hydroxylation- or halogenation reactions. Their complicated molecular architecture can be simplified using photochemical regeneration of the catalytically active, reduced FADH 2 prosthetic group. In this contribution we provide the proof-of-concept and characterization for the direct regeneration of the styrene monooxygenase from Pseudomonas. </p
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