Ag is a promising catalyst for the production of carbon monoxide (CO) via the electrochemical reduction of carbon dioxide (CO2ER). Herein, we study the role of the formate (HCOO−) intermediate *OCHO, aiming to resolve the discrepancy between the theoretical understanding and experimental performance of Ag. We show that the first coupled proton-electron transfer (CPET) step in the CO pathway competes with the Volmer step for formation of *H, whereas this Volmer step is a prerequisite for the formation of *OCHO. We show that *OCHO should form readily on the Ag surface owing to solvation and favorable binding strength. In situ surface-enhanced Raman spectroscopy (SERS) experiments give preliminary evidence of the presence of O-bound bidentate ...
Cations in an electrolyte modulate microenvironments near the catalyst surface and affect product di...
Non-noble metal molecular catalysts mediating the electrocatalytic reduction of carbon dioxide are s...
We report the discovery of a quaternary ammonium surface additive for CO2 reduction on Ag surfaces t...
Ag is a promising catalyst for the production of carbon monoxide (CO) via the electrochemical reduct...
The analysis presented in this manuscript helps bridge an important fundamental discrepancy between ...
The mechanism of CO2 reduction reaction (CO2RR) on silver electrode surfaces has been investigated b...
Converting carbon dioxide (CO2) into liquid fuels and synthesis gas is a world-wide priority. But th...
Electrocatalysis of carbon dioxide can provide a valuable pathway towards the sustainable production...
The aimed reduction of fossil carbon sources in our society does not only includes fossil fuels but ...
Converting carbon dioxide (CO_2) into liquid fuels and synthesis gas is a world-wide priority. But t...
The electrocatalytic CO2 reduction reaction (CO2RR) is one of the key technologies of the clean ener...
We have explored functionalizing metal catalysts with surface ligands as an approach to facilitate e...
We have explored functionalizing metal catalysts with surface ligands as an approach to facilitate e...
Electrocatalytic and plasma-activated processes receive increasing attention in catalysis. Density f...
For the electrochemical CO2 reduction reaction, different metal catalysts produce different products...
Cations in an electrolyte modulate microenvironments near the catalyst surface and affect product di...
Non-noble metal molecular catalysts mediating the electrocatalytic reduction of carbon dioxide are s...
We report the discovery of a quaternary ammonium surface additive for CO2 reduction on Ag surfaces t...
Ag is a promising catalyst for the production of carbon monoxide (CO) via the electrochemical reduct...
The analysis presented in this manuscript helps bridge an important fundamental discrepancy between ...
The mechanism of CO2 reduction reaction (CO2RR) on silver electrode surfaces has been investigated b...
Converting carbon dioxide (CO2) into liquid fuels and synthesis gas is a world-wide priority. But th...
Electrocatalysis of carbon dioxide can provide a valuable pathway towards the sustainable production...
The aimed reduction of fossil carbon sources in our society does not only includes fossil fuels but ...
Converting carbon dioxide (CO_2) into liquid fuels and synthesis gas is a world-wide priority. But t...
The electrocatalytic CO2 reduction reaction (CO2RR) is one of the key technologies of the clean ener...
We have explored functionalizing metal catalysts with surface ligands as an approach to facilitate e...
We have explored functionalizing metal catalysts with surface ligands as an approach to facilitate e...
Electrocatalytic and plasma-activated processes receive increasing attention in catalysis. Density f...
For the electrochemical CO2 reduction reaction, different metal catalysts produce different products...
Cations in an electrolyte modulate microenvironments near the catalyst surface and affect product di...
Non-noble metal molecular catalysts mediating the electrocatalytic reduction of carbon dioxide are s...
We report the discovery of a quaternary ammonium surface additive for CO2 reduction on Ag surfaces t...