44 pages, 17 figures, 6 tables, 50 references. Other author's papers can be downloaded at http://www.denys-dutykh.com/International audienceThis work presents an efficient numerical method based on spectral expansions for simulation of heat and moisture diffusive transfers through multilayered porous materials. Traditionally, by using the finite-difference approach, the problem is discretized in time and space domains (Method of lines) to obtain a large system of coupled Ordinary Differential Equations (ODEs), which is computationally expensive. To avoid such a cost, this paper proposes a reduced-order method that is faster and accurate, using a much smaller system of ODEs. To demonstrate the benefits of this approach, tree case studies are...