We report a desymmetrization of cyclohexadienones by intramolecular conjugate addition of a tethered dithiane nucleophile. Mild reaction conditions allow the formation of diversely functionalized fused bicyclic lactones. The products participate in facially selective additions from the convex surface, leading to allylic alcohol derivative
An S-(2,2,2-trifluoroethyl) 1,3-dithiane-2-carbothioate has been successfully employed as acyl anion...
General approaches to the construction and functionalization of cyclohexane moieties were developed ...
Herein we present the development of asymmetric deacylative allylation of ketone enolates. The react...
We report a desymmetrization of cyclohexadienones by intramolecular conjugate addition of a tethered...
Highly enantioselective intramolecular RC reactions via desymmetrization of cyclohexadienones have b...
I. Asymmetric Organocatalytic Reductive Coupling Reactions between Isatins and Aldehydes A f...
The versatility of intramolecular carbolithiation of simple unactivated alkenes to yield cyclopentyl...
A bifunctional iminophosphorane (BIMP)‐catalysed enantioselective synthesis of α,β‐unsaturated cyclo...
An asymmetric oxa-Michael/Michael cascade reaction of p-quinols and α,β-unsaturated aldehydes provid...
Enantioselective conjugate addition (ECA) reactions between organometallic reagents and cyclohexadie...
The title heterocyclic alcohol readily generates a sulfur-substituted allylic cation upon simple tre...
This thesis describes the development of diastereotopic group selective processes allowing the desym...
We describe a highly enantioselective Diels–Alder reaction of cross‐conjugated cyclohexadienones wit...
A direct aminocatalytic synthesis has been developed for the chemo-, regio-, diastereo-, and enantio...
[EN]Hydrazones derived from cycloalkenones undergo an enantioselective transannular formal (3 + 2) c...
An S-(2,2,2-trifluoroethyl) 1,3-dithiane-2-carbothioate has been successfully employed as acyl anion...
General approaches to the construction and functionalization of cyclohexane moieties were developed ...
Herein we present the development of asymmetric deacylative allylation of ketone enolates. The react...
We report a desymmetrization of cyclohexadienones by intramolecular conjugate addition of a tethered...
Highly enantioselective intramolecular RC reactions via desymmetrization of cyclohexadienones have b...
I. Asymmetric Organocatalytic Reductive Coupling Reactions between Isatins and Aldehydes A f...
The versatility of intramolecular carbolithiation of simple unactivated alkenes to yield cyclopentyl...
A bifunctional iminophosphorane (BIMP)‐catalysed enantioselective synthesis of α,β‐unsaturated cyclo...
An asymmetric oxa-Michael/Michael cascade reaction of p-quinols and α,β-unsaturated aldehydes provid...
Enantioselective conjugate addition (ECA) reactions between organometallic reagents and cyclohexadie...
The title heterocyclic alcohol readily generates a sulfur-substituted allylic cation upon simple tre...
This thesis describes the development of diastereotopic group selective processes allowing the desym...
We describe a highly enantioselective Diels–Alder reaction of cross‐conjugated cyclohexadienones wit...
A direct aminocatalytic synthesis has been developed for the chemo-, regio-, diastereo-, and enantio...
[EN]Hydrazones derived from cycloalkenones undergo an enantioselective transannular formal (3 + 2) c...
An S-(2,2,2-trifluoroethyl) 1,3-dithiane-2-carbothioate has been successfully employed as acyl anion...
General approaches to the construction and functionalization of cyclohexane moieties were developed ...
Herein we present the development of asymmetric deacylative allylation of ketone enolates. The react...
DOI
Add to ORKG