First-principles study of defects in CuGaO2

  • Fang, ZJ
  • Fang, C
  • Shi, LJ
  • Liu, YH
  • He, MC
  • Fang, ZJ, China Univ Min & Technol, Sch Mech & Civil Engn, Beijing 100083, Peoples R China. 电子邮箱地址: nnfang@semi.ac.cn
Publication date
January 2008

Abstract

Using the first-principles methods, we study the electronic structure, intrinsic and extrinsic defects doping in transparent conducting oxides CuGaO2. Intrinsic defects, acceptor-type and donor-type extrinsic defects in their relevant charge state are considered. The calculation result show that copper vacancy and oxygen interstitial are the relevant defects in CuGaO2. In addition, copper vacancy is the most efficient acceptor. Substituting Be for Ga is the prominent acceptor, and substituting Ca for Cu is the prominent donors in CuGaO2. Our calculation results are expected to be a guide for preparing n-type and p-type materials in CuGaO2

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