Whereas the cleavage of alkenes by ozone typically generates peroxide intermediates that must be decomposed in an accompanying step, ozonolysis in the presence of pyridine directly generates ketones or aldehydes through a process that neither consumes pyridine nor generates any detectable peroxides. The reaction is hypothesized to involve nucleophile-promoted fragmentation of carbonyl oxides via formation of zwitterionic peroxyacetals
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Whereas the cleavage of alkenes by ozone typically generates peroxide intermediates that must be dec...
This account describes the development of methodologies for ‘reductive’ ozonolysis, the direct ozono...
This account describes the development of methodologies for ‘reductive’ ozonolysis, the direct ozono...
Several variants of reductive ozonolysis, defined here as the in situ generation of aldehydes or ket...
Peroxides are members of a class of underutilized but highly advantageous functional groups. The per...
Peroxides are members of a class of underutilized but highly advantageous functional groups. The per...
Peroxides are members of a class of underutilized but highly advantageous functional groups. The per...
Peroxides are members of a class of underutilized but highly advantageous functional groups. The per...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Whereas the cleavage of alkenes by ozone typically generates peroxide intermediates that must be dec...
This account describes the development of methodologies for ‘reductive’ ozonolysis, the direct ozono...
This account describes the development of methodologies for ‘reductive’ ozonolysis, the direct ozono...
Several variants of reductive ozonolysis, defined here as the in situ generation of aldehydes or ket...
Peroxides are members of a class of underutilized but highly advantageous functional groups. The per...
Peroxides are members of a class of underutilized but highly advantageous functional groups. The per...
Peroxides are members of a class of underutilized but highly advantageous functional groups. The per...
Peroxides are members of a class of underutilized but highly advantageous functional groups. The per...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...
Ozone, first discovered in the mid 1800’s, is a triatomic allotrope of oxygen that is a powerful oxi...